Activation of the M-CO Bond in Transition-Metal Complexes. Fe2(CO)6(SMe)2 and Phosphine-Substituted Derivatives as Good Catalysts in Metal Carbonyl Substitution Reactions

Silvio Alme; Mauro Botta; Roberto Gobetto; Domenico Osella

doi:10.1021/om00127a036

Activation of the M-CO Bond in Transition-Metal Complexes. Fe₂(CO)₆(SMe)₂ and Phosphine-Substituted Derivatives as Good Catalysts in Metal Carbonyl Substitution Reactions

Silvio Alme, Mauro Botta, Roberto Gobetto, Domenico Osella

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The catalytic activity of Fe₂(CO)₆(SMe)₂ in CO substitution reactions on several transition-metal carbonyl complexes is reported and compared with the results obtained with other reagents. Experimental evidence has been gained to support the view that radical species are involved in these reactions and a possible pathway is proposed to explain the catalytic cycle.

Lingua originale	Inglese
pagine (da-a)	1475-1476
Numero di pagine	2
Rivista	Organometallics
Volume	4
Numero di pubblicazione	8
DOI	https://doi.org/10.1021/om00127a036
Stato di pubblicazione	Pubblicato - ago 1985
Pubblicato esternamente	Sì

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10.1021/om00127a036

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title = "Activation of the M-CO Bond in Transition-Metal Complexes. Fe2(CO)6(SMe)2 and Phosphine-Substituted Derivatives as Good Catalysts in Metal Carbonyl Substitution Reactions",

abstract = "The catalytic activity of Fe2(CO)6(SMe)2 in CO substitution reactions on several transition-metal carbonyl complexes is reported and compared with the results obtained with other reagents. Experimental evidence has been gained to support the view that radical species are involved in these reactions and a possible pathway is proposed to explain the catalytic cycle.",

author = "Silvio Alme and Mauro Botta and Roberto Gobetto and Domenico Osella",

year = "1985",

month = aug,

doi = "10.1021/om00127a036",

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pages = "1475--1476",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "8",

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Activation of the M-CO Bond in Transition-Metal Complexes. Fe₂(CO)₆(SMe)₂ and Phosphine-Substituted Derivatives as Good Catalysts in Metal Carbonyl Substitution Reactions. / Alme, Silvio; Botta, Mauro; Gobetto, Roberto et al.
In: Organometallics, Vol. 4, N. 8, 08.1985, pag. 1475-1476.

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

TY - JOUR

T1 - Activation of the M-CO Bond in Transition-Metal Complexes. Fe2(CO)6(SMe)2 and Phosphine-Substituted Derivatives as Good Catalysts in Metal Carbonyl Substitution Reactions

AU - Alme, Silvio

AU - Botta, Mauro

AU - Gobetto, Roberto

AU - Osella, Domenico

PY - 1985/8

Y1 - 1985/8

N2 - The catalytic activity of Fe2(CO)6(SMe)2 in CO substitution reactions on several transition-metal carbonyl complexes is reported and compared with the results obtained with other reagents. Experimental evidence has been gained to support the view that radical species are involved in these reactions and a possible pathway is proposed to explain the catalytic cycle.

AB - The catalytic activity of Fe2(CO)6(SMe)2 in CO substitution reactions on several transition-metal carbonyl complexes is reported and compared with the results obtained with other reagents. Experimental evidence has been gained to support the view that radical species are involved in these reactions and a possible pathway is proposed to explain the catalytic cycle.

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U2 - 10.1021/om00127a036

DO - 10.1021/om00127a036

M3 - Article

SN - 0276-7333

VL - 4

SP - 1475

EP - 1476

JO - Organometallics

JF - Organometallics

IS - 8