A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

Antonio Scafuri; Riccardo Vivani; FABIO CARNIATO; LORENZO TEI; Mauro BOTTA; Marco Taddei; Ferdinando Costantino

doi:10.1039/c5dt02808f

A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

Antonio Scafuri
, Riccardo Vivani
, FABIO CARNIATO
, LORENZO TEI
, Mauro BOTTA
, Marco Taddei
, Ferdinando Costantino

Dipartimento di Scienze e Innovazione Tecnologica

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

Lingua originale	Inglese
pagine (da-a)	19072-19075
Numero di pagine	4
Rivista	Dalton Transactions
Volume	44
Numero di pubblicazione	44
DOI	https://doi.org/10.1039/c5dt02808f
Stato di pubblicazione	Pubblicato - 2015

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10.1039/c5dt02808f

http://hdl.handle.net/11579/69971

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title = "A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework",

abstract = "Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.",

author = "Antonio Scafuri and Riccardo Vivani and FABIO CARNIATO and LORENZO TEI and Mauro BOTTA and Marco Taddei and Ferdinando Costantino",

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AU - Scafuri, Antonio

AU - Vivani, Riccardo

AU - CARNIATO, FABIO

AU - TEI, LORENZO

AU - BOTTA, Mauro

AU - Taddei, Marco

AU - Costantino, Ferdinando

PY - 2015

Y1 - 2015

N2 - Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

AB - Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

UR - https://iris.uniupo.it/handle/11579/69971

U2 - 10.1039/c5dt02808f

DO - 10.1039/c5dt02808f

M3 - Article

SN - 1477-9234

VL - 44

SP - 19072

EP - 19075

JO - Dalton Transactions

JF - Dalton Transactions

IS - 44

ER -

A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

Abstract

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