A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(iii) ions located in the framework

Antonio Scafuri, Riccardo Vivani, Fabio Carniato, Lorenzo Tei, Mauro Botta, Marco Taddei, Ferdinando Costantino

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

Novel Gd(iii) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

Lingua originaleInglese
pagine (da-a)19072-19075
Numero di pagine4
RivistaDalton Transactions
Volume44
Numero di pubblicazione44
DOI
Stato di pubblicazionePubblicato - 12 ott 2015

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