A novel metal-ligand Iodo-bridged Lead(II) compound: Synthesis, crystal structure, thermal properties, and DFT calculations of [Pb(dmp)I 2]n

Behrouz Shaabani, Babak Mirtamizdoust, Davide Viterbo, Gianluca Croce, Hassan Hammud

Risultato della ricerca: Contributo su rivistaArticolo in rivistapeer review

Abstract

A novel 1D PbII coordination polymer [Pb(dmp)I2] n (1) (dmp = 2,9-dimethyl-1,10-phenanthroline) containing a Pb 2-(μ-I)2 unit was synthesized and characterized by elemental analysis, IR, 1H NMR, and 13C NMR spectroscopy and studied by thermal, analysis as well. as X-ray crystallography. The single-crystal X-ray data show that the coordination number of PbII ions is six, i.e. PbN2I4 with "stereo-chemically active" electron lone pairs, and the coordination, sphere is asymmetrical. They also show that the chains interact with each other through π-π stacking interactions, which create a 3D framework. The structure of the title complex has been optimized by density functional theory calculations. The calculated structural, parameters and the IR spectra of the title complex are in agreement with the crystal, structure.

Lingua originaleInglese
pagine (da-a)1596-1600
Numero di pagine5
RivistaZeitschrift fur Anorganische und Allgemeine Chemie
Volume636
Numero di pubblicazione8
DOI
Stato di pubblicazionePubblicato - ago 2010
Pubblicato esternamente

Fingerprint

Entra nei temi di ricerca di 'A novel metal-ligand Iodo-bridged Lead(II) compound: Synthesis, crystal structure, thermal properties, and DFT calculations of [Pb(dmp)I 2]n'. Insieme formano una fingerprint unica.

Cita questo