A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os3 carbonyl clusters

S. F.A. Kettle; E. Diana; R. Rossetti; P. L. Stanghellini

doi:10.1016/S0020-1693(01)00453-4

A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os₃ carbonyl clusters

S. F.A. Kettle, E. Diana, R. Rossetti, P. L. Stanghellini

Risultato della ricerca: Contributo su rivista › Articolo in rivista › peer review

Abstract

The ν(M-M) Raman spectra of some twenty doubly bridged Os₃ carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm^-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.

Lingua originale	Inglese
pagine (da-a)	75-82
Numero di pagine	8
Rivista	Inorganica Chimica Acta
Volume	319
Numero di pubblicazione	1-2
DOI	https://doi.org/10.1016/S0020-1693(01)00453-4
Stato di pubblicazione	Pubblicato - 16 lug 2001
Pubblicato esternamente	Sì

Accesso al documento

10.1016/S0020-1693(01)00453-4

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title = "A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os3 carbonyl clusters",

abstract = "The ν(M-M) Raman spectra of some twenty doubly bridged Os3 carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.",

keywords = "Carbonyl complexes, Cluster complexes, Osmium complexes, Raman spectroscopy",

author = "Kettle, {S. F.A.} and E. Diana and R. Rossetti and Stanghellini, {P. L.}",

year = "2001",

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T1 - A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os3 carbonyl clusters

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Rossetti, R.

AU - Stanghellini, P. L.

PY - 2001/7/16

Y1 - 2001/7/16

N2 - The ν(M-M) Raman spectra of some twenty doubly bridged Os3 carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.

AB - The ν(M-M) Raman spectra of some twenty doubly bridged Os3 carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.

KW - Carbonyl complexes

KW - Cluster complexes

KW - Osmium complexes

KW - Raman spectroscopy

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U2 - 10.1016/S0020-1693(01)00453-4

DO - 10.1016/S0020-1693(01)00453-4

M3 - Article

SN - 0020-1693

VL - 319

SP - 75

EP - 82

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2