UV photoelectron spectra of some organometallic carbonyl osmium clusters

Gaetano Granozzi; Renzo Bertoncello; Silvio Aime; Domenico Osella

doi:10.1016/S0022-328X(00)90285-7

UV photoelectron spectra of some organometallic carbonyl osmium clusters

Gaetano Granozzi
, Renzo Bertoncello
, Silvio Aime
, Domenico Osella

Research output: Contribution to journal › Article › peer-review

Abstract

The He(I) excited PE spectra of HOs₃(μ₃-L)(CO)₉ (L allenyl, allyl) and of HOs₃(μ₂-vinyl)(CO)₁₀ are presented. Some gross spectral features are discussed on the basis of a direct comparison with previous results for Os₃(CO)₁₂ and the alkynyl corresponding cluster derivative. Large perturbations in the OsOs bonding levels are induced by the bridging hydride and the interaction with the organic substrate.

Original language	English
Pages (from-to)	C27-C30
Journal	Journal of Organometallic Chemistry
Volume	229
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)90285-7
Publication status	Published - 20 Apr 1982
Externally published	Yes

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10.1016/S0022-328X(00)90285-7

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title = "UV photoelectron spectra of some organometallic carbonyl osmium clusters",

abstract = "The He(I) excited PE spectra of HOs3(μ3-L)(CO)9 (L allenyl, allyl) and of HOs3(μ2-vinyl)(CO)10 are presented. Some gross spectral features are discussed on the basis of a direct comparison with previous results for Os3(CO)12 and the alkynyl corresponding cluster derivative. Large perturbations in the OsOs bonding levels are induced by the bridging hydride and the interaction with the organic substrate.",

author = "Gaetano Granozzi and Renzo Bertoncello and Silvio Aime and Domenico Osella",

year = "1982",

month = apr,

day = "20",

doi = "10.1016/S0022-328X(00)90285-7",

language = "English",

volume = "229",

pages = "C27--C30",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

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TY - JOUR

T1 - UV photoelectron spectra of some organometallic carbonyl osmium clusters

AU - Granozzi, Gaetano

AU - Bertoncello, Renzo

AU - Aime, Silvio

AU - Osella, Domenico

PY - 1982/4/20

Y1 - 1982/4/20

N2 - The He(I) excited PE spectra of HOs3(μ3-L)(CO)9 (L allenyl, allyl) and of HOs3(μ2-vinyl)(CO)10 are presented. Some gross spectral features are discussed on the basis of a direct comparison with previous results for Os3(CO)12 and the alkynyl corresponding cluster derivative. Large perturbations in the OsOs bonding levels are induced by the bridging hydride and the interaction with the organic substrate.

AB - The He(I) excited PE spectra of HOs3(μ3-L)(CO)9 (L allenyl, allyl) and of HOs3(μ2-vinyl)(CO)10 are presented. Some gross spectral features are discussed on the basis of a direct comparison with previous results for Os3(CO)12 and the alkynyl corresponding cluster derivative. Large perturbations in the OsOs bonding levels are induced by the bridging hydride and the interaction with the organic substrate.

UR - https://www.scopus.com/pages/publications/49049136385

U2 - 10.1016/S0022-328X(00)90285-7

DO - 10.1016/S0022-328X(00)90285-7

M3 - Article

SN - 0022-328X

VL - 229

SP - C27-C30

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

UV photoelectron spectra of some organometallic carbonyl osmium clusters

Abstract

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