The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M5 species

S. F.A. Kettle; E. Diana; P. L. Stanghellini; R. Della Pergola; A. Fumagalli

doi:10.1016/0020-1693(95)90083-I

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species

S. F.A. Kettle
, E. Diana
, P. L. Stanghellini
, R. Della Pergola
, A. Fumagalli

Research output: Contribution to journal › Article › peer-review

Abstract

A study of the ν(CO) spectra of six M₅ trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.

Original language	English
Pages (from-to)	407-411
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	235
Issue number	1-2
DOIs	https://doi.org/10.1016/0020-1693(95)90083-I
Publication status	Published - Jul 1995
Externally published	Yes

Keywords

Carbonyl complexes
Cluster complexes
Infrared Raman spectroscopy
Transition metal complexes

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10.1016/0020-1693(95)90083-I

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Kettle, S. F. A., Diana, E., Stanghellini, P. L., Della Pergola, R., & Fumagalli, A. (1995). The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species. Inorganica Chimica Acta, 235(1-2), 407-411. https://doi.org/10.1016/0020-1693(95)90083-I

@article{c3797e01252e4c439566667e2954550b,

title = "The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M5 species",

abstract = "A study of the ν(CO) spectra of six M5 trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.",

keywords = "Carbonyl complexes, Cluster complexes, Infrared Raman spectroscopy, Transition metal complexes",

author = "Kettle, \{S. F.A.\} and E. Diana and Stanghellini, \{P. L.\} and \{Della Pergola\}, R. and A. Fumagalli",

note = "Funding Information: We are indebtedt o Dr E. Agosti (Dipartimentod i ChimicaI ndustriale,P olitecnicod i Milano) for technical assistancwe ith the measuremenotsf the Raman spectra. Financial support from the Italian CNR (Progettob i-lateraled i ricercaf or P.L.S. and S.F.A.K.) is gratefully acknowledged.",

year = "1995",

month = jul,

doi = "10.1016/0020-1693(95)90083-I",

language = "English",

volume = "235",

pages = "407--411",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "1-2",

}

Kettle, SFA, Diana, E, Stanghellini, PL, Della Pergola, R & Fumagalli, A 1995, 'The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species', Inorganica Chimica Acta, vol. 235, no. 1-2, pp. 407-411. https://doi.org/10.1016/0020-1693(95)90083-I

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species. / Kettle, S. F.A.; Diana, E.; Stanghellini, P. L. et al.
In: Inorganica Chimica Acta, Vol. 235, No. 1-2, 07.1995, p. 407-411.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M5 species

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Stanghellini, P. L.

AU - Della Pergola, R.

AU - Fumagalli, A.

N1 - Funding Information: We are indebtedt o Dr E. Agosti (Dipartimentod i ChimicaI ndustriale,P olitecnicod i Milano) for technical assistancwe ith the measuremenotsf the Raman spectra. Financial support from the Italian CNR (Progettob i-lateraled i ricercaf or P.L.S. and S.F.A.K.) is gratefully acknowledged.

PY - 1995/7

Y1 - 1995/7

N2 - A study of the ν(CO) spectra of six M5 trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.

AB - A study of the ν(CO) spectra of six M5 trigonal bipyramidal cluster carbonyls shows that the patterns observed are consistent with the postulate that the bridgingspectra are more structure-sensitive than are the terminal ones. A qualitative suggestion is made concerning predictions for species with bridge CO groups with significantly different ν(CO) zeroth-order frequency differences.

KW - Carbonyl complexes

KW - Cluster complexes

KW - Infrared Raman spectroscopy

KW - Transition metal complexes

UR - https://www.scopus.com/pages/publications/0000068984

U2 - 10.1016/0020-1693(95)90083-I

DO - 10.1016/0020-1693(95)90083-I

M3 - Article

SN - 0020-1693

VL - 235

SP - 407

EP - 411

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metals carbonyl cluster compounds Part 2. Some M₅ species

Abstract

Keywords

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