The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metal carbonyl cluster compounds

S. F.A. Kettle; E. Diana; R. Rossetti; P. L. Stanghellini; R. Della Pergola; L. Garlaschelli

doi:10.1016/0020-1693(94)04216-0

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metal carbonyl cluster compounds

S. F.A. Kettle, E. Diana, R. Rossetti, P. L. Stanghellini, R. Della Pergola, L. Garlaschelli

Research output: Contribution to journal › Article › peer-review

Abstract

The ν(CO) spectra of a series of transition metal cluster compounds are compared with their structures. Despite considerable structural differences, the spectra in the terminal region are surprisingly invariant. Rather more variation is shown in the bridging region spectra; it proves possible to understand these variations in terms of a qualitative model. A generalisation concerning bridging region spectra is presented.

Original language	English
Pages (from-to)	241-246
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	227
Issue number	2
DOIs	https://doi.org/10.1016/0020-1693(94)04216-0
Publication status	Published - 15 Dec 1994
Externally published	Yes

Keywords

Bridging carbonyl
Clusters
Infrared Raman spectroscopy

Access to Document

10.1016/0020-1693(94)04216-0

Cite this

@article{7d62b987e2bd4f89b7b6c03c4f3bcafa,

title = "The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metal carbonyl cluster compounds",

abstract = "The ν(CO) spectra of a series of transition metal cluster compounds are compared with their structures. Despite considerable structural differences, the spectra in the terminal region are surprisingly invariant. Rather more variation is shown in the bridging region spectra; it proves possible to understand these variations in terms of a qualitative model. A generalisation concerning bridging region spectra is presented.",

keywords = "Bridging carbonyl, Clusters, Infrared Raman spectroscopy",

author = "Kettle, {S. F.A.} and E. Diana and R. Rossetti and Stanghellini, {P. L.} and {Della Pergola}, R. and L. Garlaschelli",

year = "1994",

month = dec,

day = "15",

doi = "10.1016/0020-1693(94)04216-0",

language = "English",

volume = "227",

pages = "241--246",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metal carbonyl cluster compounds

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Rossetti, R.

AU - Stanghellini, P. L.

AU - Della Pergola, R.

AU - Garlaschelli, L.

PY - 1994/12/15

Y1 - 1994/12/15

N2 - The ν(CO) spectra of a series of transition metal cluster compounds are compared with their structures. Despite considerable structural differences, the spectra in the terminal region are surprisingly invariant. Rather more variation is shown in the bridging region spectra; it proves possible to understand these variations in terms of a qualitative model. A generalisation concerning bridging region spectra is presented.

AB - The ν(CO) spectra of a series of transition metal cluster compounds are compared with their structures. Despite considerable structural differences, the spectra in the terminal region are surprisingly invariant. Rather more variation is shown in the bridging region spectra; it proves possible to understand these variations in terms of a qualitative model. A generalisation concerning bridging region spectra is presented.

KW - Bridging carbonyl

KW - Clusters

KW - Infrared Raman spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=0001587291&partnerID=8YFLogxK

U2 - 10.1016/0020-1693(94)04216-0

DO - 10.1016/0020-1693(94)04216-0

M3 - Article

SN - 0020-1693

VL - 227

SP - 241

EP - 246

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metal carbonyl cluster compounds

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this