The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe3(CO)11L], L = PR3 or P(OR)3

Robert E. Benfield; Paul D. Gavens; Brian F.G. Johnson; Martin J. Mays; Silvo Aime; Luciano Milone; Domenico Osella

doi:10.1039/DT9810001535

The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe₃(CO)₁₁L], L = PR₃ or P(OR)₃

Robert E. Benfield
, Paul D. Gavens
, Brian F.G. Johnson
, Martin J. Mays
, Silvo Aime
, Luciano Milone
, Domenico Osella

Research output: Contribution to journal › Article › peer-review

Abstract

The stereodynamic behaviour of the complexes [Fe₃(CO)₁₁L] [L = PR₃ or P(OR)₃], as determined by ¹³C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M₄(CO)₁₂] (M = Co, Rh, or lr) and their derivatives.

Original language	English
Pages (from-to)	1535-1539
Number of pages	5
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/DT9810001535
Publication status	Published - 1981
Externally published	Yes

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title = "The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe3(CO)11L], L = PR3 or P(OR)3",

abstract = "The stereodynamic behaviour of the complexes [Fe3(CO)11L] [L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12] (M = Co, Rh, or lr) and their derivatives.",

author = "Benfield, \{Robert E.\} and Gavens, \{Paul D.\} and Johnson, \{Brian F.G.\} and Mays, \{Martin J.\} and Silvo Aime and Luciano Milone and Domenico Osella",

year = "1981",

doi = "10.1039/DT9810001535",

language = "English",

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journal = "Journal of the Chemical Society. Dalton Transactions",

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AU - Benfield, Robert E.

AU - Gavens, Paul D.

AU - Johnson, Brian F.G.

AU - Mays, Martin J.

AU - Aime, Silvo

AU - Milone, Luciano

AU - Osella, Domenico

PY - 1981

Y1 - 1981

N2 - The stereodynamic behaviour of the complexes [Fe3(CO)11L] [L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12] (M = Co, Rh, or lr) and their derivatives.

AB - The stereodynamic behaviour of the complexes [Fe3(CO)11L] [L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral ⇌ cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12] (M = Co, Rh, or lr) and their derivatives.

UR - https://www.scopus.com/pages/publications/37049101244

U2 - 10.1039/DT9810001535

DO - 10.1039/DT9810001535

M3 - Article

SN - 1472-7773

SP - 1535

EP - 1539

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 7

ER -

The structures and fluxional behaviour of the binary carbonyls; A new approach. Part 3. The fluxional behaviour of [fe₃(CO)₁₁L], L = PR₃ or P(OR)₃

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