The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

Sabrina Brait; Stefano Deabate; Selby A.R. Knox; Enrico Sappa

doi:10.1023/A:1016627113620

The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

Sabrina Brait
, Stefano Deabate
, Selby A.R. Knox
, Enrico Sappa

Research output: Contribution to journal › Article › peer-review

Abstract

A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.

Original language	English
Pages (from-to)	139-173
Number of pages	35
Journal	Journal of Cluster Science
Volume	12
Issue number	1
DOIs	https://doi.org/10.1023/A:1016627113620
Publication status	Published - 2001
Externally published	Yes

Keywords

Benzyne ligands
Hydrogenation catalysis (homogeneous, solid-gas, heterogeneous)
Reactivity; cluster-surface analogy
Transition metal clusters

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10.1023/A:1016627113620

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title = "The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes",

abstract = "A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.",

keywords = "Benzyne ligands, Hydrogenation catalysis (homogeneous, solid-gas, heterogeneous), Reactivity; cluster-surface analogy, Transition metal clusters",

author = "Sabrina Brait and Stefano Deabate and Knox, \{Selby A.R.\} and Enrico Sappa",

year = "2001",

doi = "10.1023/A:1016627113620",

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AU - Deabate, Stefano

AU - Knox, Selby A.R.

AU - Sappa, Enrico

PY - 2001

Y1 - 2001

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AB - A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.

KW - Benzyne ligands

KW - Hydrogenation catalysis (homogeneous, solid-gas, heterogeneous)

KW - Reactivity; cluster-surface analogy

KW - Transition metal clusters

UR - https://www.scopus.com/pages/publications/0035593988

U2 - 10.1023/A:1016627113620

DO - 10.1023/A:1016627113620

M3 - Article

SN - 1040-7278

VL - 12

SP - 139

EP - 173

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 1

ER -

The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

Abstract

Keywords

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