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Synthesis of the Sulfonate Analogue of Seminolipid via Horner-Wadsworth-Emmons Olefination

  • L FRANCHINI
  • , F COMPOSTELLA
  • , D COLOMBO
  • , Luigi PANZA
  • , F. RONCHETTI

Research output: Contribution to journalArticle

Abstract

(Figure presented) The first synthesis of the sulfonate analogue of seminolipid, the main sulfoglycolipid in mammalian sperm, is reported. Installation of the sulfonate unit was accomplished by a quite unexplored strategy based on Horner-Wadsworth-Emmons olefination on a 3 ′-keto-galactoside, followed by stereoselective double bond reduction.

Original languageEnglish
Pages (from-to)5363-5366
Number of pages4
JournalJournal of Organic Chemistry
Volume75
Publication statusPublished - 2010

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