Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic
carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic–
organometallic hybrid materials based on mesoporous SBA-15 silica

FABIO CARNIATO; Giorgio GATTI; G GERVASIO; D MARABELLO; Enrico SAPPA; ANDREA SECCO

doi:10.1016/j.ica.2010.03.001

Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica

FABIO CARNIATO
, Giorgio GATTI
, G GERVASIO
, D MARABELLO
, Enrico SAPPA
, ANDREA SECCO

Research output: Contribution to journal › Article › peer-review

Abstract

The reactions of the complexes Fe₃(CO)₁₂, H₂FeRu₃(CO)₁₃, H₂Ru₄(CO)₁₃ and CpNiRu₃(H)₃(CO)₉ with 2(diphenylphosphino)ethyl-triethoxysilane give considerable yields of the complexes Fe₃(CO)₁₀L₂ (1), H₂FeRu₃(CO)₁₀L₂ (2), Ru₄(CO)₁₀L₃ (3) and CpNiRu₃(H)₃(CO)₇L₂ (4) where L = Ph₂PCH₂CH₂Si(OEt)₃. The complexes (1-3) have been characterized by analytical and spectroscopic techniques. The structure of (4) has been determined by X-ray analysis. The presence of a phosphine containing the -Si(OEt)₃ group has been exploited for grafting complexes (3) and (4) on the mesoporous SBA-15 and the resulting inorganic-organometallic materials have been characterized by means of ICP-MS, FT-IR, DR-UV-vis spectroscopy, XRD and textural analysis.

Original language	English
Pages (from-to)	1773-1778
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	363
DOIs	https://doi.org/10.1016/j.ica.2010.03.001
Publication status	Published - 2010

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http://hdl.handle.net/11579/33934

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CARNIATO, FABIO., GATTI, G., GERVASIO, G., MARABELLO, D., SAPPA, E., & SECCO, ANDREA. (2010). Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica. Inorganica Chimica Acta, 363, 1773-1778. https://doi.org/10.1016/j.ica.2010.03.001

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title = "Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica",

abstract = "The reactions of the complexes Fe3(CO)12, H2FeRu3(CO)13, H2Ru4(CO)13 and CpNiRu3(H)3(CO)9 with 2(diphenylphosphino)ethyl-triethoxysilane give considerable yields of the complexes Fe3(CO)10L2 (1), H2FeRu3(CO)10L2 (2), Ru4(CO)10L3 (3) and CpNiRu3(H)3(CO)7L2 (4) where L = Ph2PCH2CH2Si(OEt)3. The complexes (1-3) have been characterized by analytical and spectroscopic techniques. The structure of (4) has been determined by X-ray analysis. The presence of a phosphine containing the -Si(OEt)3 group has been exploited for grafting complexes (3) and (4) on the mesoporous SBA-15 and the resulting inorganic-organometallic materials have been characterized by means of ICP-MS, FT-IR, DR-UV-vis spectroscopy, XRD and textural analysis.",

author = "FABIO CARNIATO and Giorgio GATTI and G GERVASIO and D MARABELLO and Enrico SAPPA and ANDREA SECCO",

year = "2010",

doi = "10.1016/j.ica.2010.03.001",

language = "English",

volume = "363",

pages = "1773--1778",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

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}

CARNIATO, FABIO , GATTI, G, GERVASIO, G, MARABELLO, D, SAPPA, E & SECCO, ANDREA 2010, 'Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica', Inorganica Chimica Acta, vol. 363, pp. 1773-1778. https://doi.org/10.1016/j.ica.2010.03.001

Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica. / CARNIATO, FABIO ; GATTI, Giorgio; GERVASIO, G et al.
In: Inorganica Chimica Acta, Vol. 363, 2010, p. 1773-1778.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica

AU - CARNIATO, FABIO

AU - GATTI, Giorgio

AU - GERVASIO, G

AU - MARABELLO, D

AU - SAPPA, Enrico

AU - SECCO, ANDREA

PY - 2010

Y1 - 2010

N2 - The reactions of the complexes Fe3(CO)12, H2FeRu3(CO)13, H2Ru4(CO)13 and CpNiRu3(H)3(CO)9 with 2(diphenylphosphino)ethyl-triethoxysilane give considerable yields of the complexes Fe3(CO)10L2 (1), H2FeRu3(CO)10L2 (2), Ru4(CO)10L3 (3) and CpNiRu3(H)3(CO)7L2 (4) where L = Ph2PCH2CH2Si(OEt)3. The complexes (1-3) have been characterized by analytical and spectroscopic techniques. The structure of (4) has been determined by X-ray analysis. The presence of a phosphine containing the -Si(OEt)3 group has been exploited for grafting complexes (3) and (4) on the mesoporous SBA-15 and the resulting inorganic-organometallic materials have been characterized by means of ICP-MS, FT-IR, DR-UV-vis spectroscopy, XRD and textural analysis.

AB - The reactions of the complexes Fe3(CO)12, H2FeRu3(CO)13, H2Ru4(CO)13 and CpNiRu3(H)3(CO)9 with 2(diphenylphosphino)ethyl-triethoxysilane give considerable yields of the complexes Fe3(CO)10L2 (1), H2FeRu3(CO)10L2 (2), Ru4(CO)10L3 (3) and CpNiRu3(H)3(CO)7L2 (4) where L = Ph2PCH2CH2Si(OEt)3. The complexes (1-3) have been characterized by analytical and spectroscopic techniques. The structure of (4) has been determined by X-ray analysis. The presence of a phosphine containing the -Si(OEt)3 group has been exploited for grafting complexes (3) and (4) on the mesoporous SBA-15 and the resulting inorganic-organometallic materials have been characterized by means of ICP-MS, FT-IR, DR-UV-vis spectroscopy, XRD and textural analysis.

UR - https://iris.uniupo.it/handle/11579/33934

U2 - 10.1016/j.ica.2010.03.001

DO - 10.1016/j.ica.2010.03.001

M3 - Article

SN - 0020-1693

VL - 363

SP - 1773

EP - 1778

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

CARNIATO FABIO , GATTI G, GERVASIO G, MARABELLO D, SAPPA E, SECCO ANDREA. Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica. Inorganica Chimica Acta. 2010;363:1773-1778. doi: 10.1016/j.ica.2010.03.001

Synthesis and structure of new phosphine-substituted homo- and hetero-bimetallic carbonyl clusters of iron, ruthenium and nickel. Characterization of two inorganic– organometallic hybrid materials based on mesoporous SBA-15 silica

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