Synthesis and Comparative Anion Binding Profiles of Two Diacqua Eu(III) Complexes

DANIELA IMPERIO; Giovanni Battista GIOVENZANA; G. L. PARKER D LAW; J. W. WALTON

doi:10.1039/c0dt00773k

Synthesis and Comparative Anion Binding Profiles of Two Diacqua Eu(III) Complexes

DANIELA IMPERIO
, Giovanni Battista GIOVENZANA
, G. L. PARKER D LAW
, J. W. WALTON

Research output: Contribution to journal › Article › peer-review

Abstract

Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

Original language	English
Pages (from-to)	9897-9903
Number of pages	7
Journal	Dalton Transactions
Volume	39
DOIs	https://doi.org/10.1039/c0dt00773k
Publication status	Published - 2010

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10.1039/c0dt00773k

http://hdl.handle.net/11579/24465

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@article{5add045bbb9448d3ab7cd7d908b21d02,

title = "Synthesis and Comparative Anion Binding Profiles of Two Diacqua Eu(III) Complexes",

abstract = "Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).",

author = "DANIELA IMPERIO and GIOVENZANA, \{Giovanni Battista\} and LAW, \{G. L. PARKER D\} and WALTON, \{J. W.\}",

year = "2010",

doi = "10.1039/c0dt00773k",

language = "English",

volume = "39",

pages = "9897--9903",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Synthesis and Comparative Anion Binding Profiles of Two Diacqua Eu(III) Complexes

AU - IMPERIO, DANIELA

AU - GIOVENZANA, Giovanni Battista

AU - LAW, G. L. PARKER D

AU - WALTON, J. W.

PY - 2010

Y1 - 2010

N2 - Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

AB - Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

UR - https://iris.uniupo.it/handle/11579/24465

U2 - 10.1039/c0dt00773k

DO - 10.1039/c0dt00773k

M3 - Article

SN - 1477-9226

VL - 39

SP - 9897

EP - 9903

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Synthesis and Comparative Anion Binding Profiles of Two Diacqua Eu(III) Complexes

Abstract

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