Structure-activity relationships in the partial oxidation of methane to formaldehyde on Fe-x/SiO2 catalysts

F Arena; Giorgio GATTI; S Coluccia; G Martra; A. Parmaliana

Structure-activity relationships in the partial oxidation of methane to formaldehyde on Fe-x/SiO2 catalysts

F Arena
, Giorgio GATTI
, S Coluccia
, G Martra
, A. Parmaliana

Department of Sustainable Development and Ecological Transition

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

The effects of the preparation method on structures and dispersion of FeO_x/SiO₂ catalysts have been investigated by DR-UV-Vis, FTIR and TPR measurements. The efficiency of the preparation route based on "adsorption-precipitation" of Fe²⁺ (ADS/PRC), in enhancing the oxide dispersion is ascertained. The performance of ADS/PRC catalysts in the partial oxidation of CH₄ to HCHO (MPO) is compared with that of conventional systems obtained by "incipient wetness" of silica with aqueous solutions of Fe^III (INC/WET). The ADS/PRC method, enabling a higher dispersion of the active phase, provides very effective MPO catalysts.

Original language	English
Title of host publication	NATURAL GAS CONVERSION VII
Publisher	Elsevier
Pages	535-540
Number of pages	6
Volume	147
ISBN (Print)	0444515992
Publication status	Published - 2004

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title = "Structure-activity relationships in the partial oxidation of methane to formaldehyde on Fe-x/SiO2 catalysts",

abstract = "The effects of the preparation method on structures and dispersion of FeOx/SiO2 catalysts have been investigated by DR-UV-Vis, FTIR and TPR measurements. The efficiency of the preparation route based on {"}adsorption-precipitation{"} of Fe2+ (ADS/PRC), in enhancing the oxide dispersion is ascertained. The performance of ADS/PRC catalysts in the partial oxidation of CH4 to HCHO (MPO) is compared with that of conventional systems obtained by {"}incipient wetness{"} of silica with aqueous solutions of FeIII (INC/WET). The ADS/PRC method, enabling a higher dispersion of the active phase, provides very effective MPO catalysts.",

author = "F Arena and Giorgio GATTI and S Coluccia and G Martra and A. Parmaliana",

year = "2004",

language = "English",

isbn = "0444515992",

volume = "147",

pages = "535--540",

booktitle = "NATURAL GAS CONVERSION VII",

publisher = "Elsevier",

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TY - CHAP

T1 - Structure-activity relationships in the partial oxidation of methane to formaldehyde on Fe-x/SiO2 catalysts

AU - Arena, F

AU - GATTI, Giorgio

AU - Coluccia, S

AU - Martra, G

AU - Parmaliana, A.

PY - 2004

Y1 - 2004

N2 - The effects of the preparation method on structures and dispersion of FeOx/SiO2 catalysts have been investigated by DR-UV-Vis, FTIR and TPR measurements. The efficiency of the preparation route based on "adsorption-precipitation" of Fe2+ (ADS/PRC), in enhancing the oxide dispersion is ascertained. The performance of ADS/PRC catalysts in the partial oxidation of CH4 to HCHO (MPO) is compared with that of conventional systems obtained by "incipient wetness" of silica with aqueous solutions of FeIII (INC/WET). The ADS/PRC method, enabling a higher dispersion of the active phase, provides very effective MPO catalysts.

AB - The effects of the preparation method on structures and dispersion of FeOx/SiO2 catalysts have been investigated by DR-UV-Vis, FTIR and TPR measurements. The efficiency of the preparation route based on "adsorption-precipitation" of Fe2+ (ADS/PRC), in enhancing the oxide dispersion is ascertained. The performance of ADS/PRC catalysts in the partial oxidation of CH4 to HCHO (MPO) is compared with that of conventional systems obtained by "incipient wetness" of silica with aqueous solutions of FeIII (INC/WET). The ADS/PRC method, enabling a higher dispersion of the active phase, provides very effective MPO catalysts.

UR - https://iris.uniupo.it/handle/11579/48760

M3 - Chapter

SN - 0444515992

VL - 147

SP - 535

EP - 540

BT - NATURAL GAS CONVERSION VII

PB - Elsevier

ER -

Structure-activity relationships in the partial oxidation of methane to formaldehyde on Fe-x/SiO2 catalysts

Abstract

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