Stevens Rearrangement as a Tool for the Structural Modification of Polyaminopolycarboxylic Ligands

Giovanni Battista GIOVENZANA; DANIELA IMPERIO; L LATTUADA; F. UGGERI

doi:10.1039/C0OB00909A

Stevens Rearrangement as a Tool for the Structural Modification of Polyaminopolycarboxylic Ligands

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Abstract

Polyaminopolycarboxylic acids are a well known class of ligands employed for metal ion complexation. Despite the large commercial availability, reports of their use as substrates for direct structural modifications are rare. Herein we report a simple and efficient protocol for the preparation of substituted polyaminopolycarboxylic ligands relying on a one-pot N-alkylation–Stevens rearrangement cascade.

Original language	English
Pages (from-to)	679-681
Number of pages	3
Journal	Organic and Biomolecular Chemistry
Volume	9
DOIs	https://doi.org/10.1039/C0OB00909A
Publication status	Published - 2011

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10.1039/C0OB00909A

http://hdl.handle.net/11579/15943

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title = "Stevens Rearrangement as a Tool for the Structural Modification of Polyaminopolycarboxylic Ligands",

abstract = "Polyaminopolycarboxylic acids are a well known class of ligands employed for metal ion complexation. Despite the large commercial availability, reports of their use as substrates for direct structural modifications are rare. Herein we report a simple and efficient protocol for the preparation of substituted polyaminopolycarboxylic ligands relying on a one-pot N-alkylation{\textendash}Stevens rearrangement cascade.",

author = "GIOVENZANA, \{Giovanni Battista\} and DANIELA IMPERIO and L LATTUADA and F. UGGERI",

year = "2011",

doi = "10.1039/C0OB00909A",

language = "English",

volume = "9",

pages = "679--681",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

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T1 - Stevens Rearrangement as a Tool for the Structural Modification of Polyaminopolycarboxylic Ligands

AU - GIOVENZANA, Giovanni Battista

AU - IMPERIO, DANIELA

AU - LATTUADA, L

AU - UGGERI, F.

PY - 2011

Y1 - 2011

N2 - Polyaminopolycarboxylic acids are a well known class of ligands employed for metal ion complexation. Despite the large commercial availability, reports of their use as substrates for direct structural modifications are rare. Herein we report a simple and efficient protocol for the preparation of substituted polyaminopolycarboxylic ligands relying on a one-pot N-alkylation–Stevens rearrangement cascade.

AB - Polyaminopolycarboxylic acids are a well known class of ligands employed for metal ion complexation. Despite the large commercial availability, reports of their use as substrates for direct structural modifications are rare. Herein we report a simple and efficient protocol for the preparation of substituted polyaminopolycarboxylic ligands relying on a one-pot N-alkylation–Stevens rearrangement cascade.

UR - https://iris.uniupo.it/handle/11579/15943

U2 - 10.1039/C0OB00909A

DO - 10.1039/C0OB00909A

M3 - Article

SN - 1477-0520

VL - 9

SP - 679

EP - 681

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

ER -

Stevens Rearrangement as a Tool for the Structural Modification of Polyaminopolycarboxylic Ligands

Abstract

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