TY - JOUR
T1 - Solid-state adducts between C60 and decamethylferrocene
AU - Arrais, Aldo
AU - Diana, Eliano
AU - Gobetto, Roberto
AU - Milanesio, Marco
AU - Viterbo, Davide
AU - Stanghellini, Pier Luigi
PY - 2003/3
Y1 - 2003/3
N2 - Co-deposition from concentrated solutions of C60 and Fe[C5(CH3)5]2 affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, 13C CPMAS NMR and vibrational spectroscopy, which showed it to be a cocrystalline adduct of C60 and Fe[C5(CH3)5]2 with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible.
AB - Co-deposition from concentrated solutions of C60 and Fe[C5(CH3)5]2 affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, 13C CPMAS NMR and vibrational spectroscopy, which showed it to be a cocrystalline adduct of C60 and Fe[C5(CH3)5]2 with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible.
KW - Donor-acceptor systems
KW - Fullerenes
KW - Infrared spectroscopy
KW - Raman spectroscopy
KW - Sandwich complexes
UR - http://www.scopus.com/inward/record.url?scp=0037354806&partnerID=8YFLogxK
U2 - 10.1002/ejic.200390153
DO - 10.1002/ejic.200390153
M3 - Article
SN - 1434-1948
SP - 1186
EP - 1192
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 6
ER -