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Sol-gel silica films embedding NIR- emitting Yb-quinolinolate complexes

  • Cristiana Figus
  • , Francesco Quochi
  • , Flavia Artizzu
  • , Giacomo Piana
  • , Michele Saba
  • , Maria Laura Mercuri
  • , Angela Serpe
  • , Paola Deplano
  • , Andrea Mura
  • , Giovanni Bongiovanni

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Sol-gel silica thin films embedding an ytterbium quinolinolato complex (YbClQ4) have been obtained using different alkoxides. Homogeneous, crack- and defect-free thin films of optical quality have been successfully deposited on glass substrate by dip-coating. The silica thin films have been characterized by time-resolved photoluminescence. The luminescence properties of the YbClQ4 are preserved in silica films prepared through an optimized sol-gel approach. The excited state lifetime of the lanthanide is comparable to those observed in bulk and longer than the corresponding ones in solution.

Original languageEnglish
Title of host publicationFundamentals and Applications in Silica and Advanced Dielectrics, SiO 2014 - X International Symposium on SiO2, Advanced Dielectrics and Related Devices
EditorsPier Carlo Ricci, Carlo Maria Carbonaro
PublisherAmerican Institute of Physics Inc.
Pages37-42
Number of pages6
ISBN (Electronic)9780735412613
DOIs
Publication statusPublished - 21 Oct 2014
Externally publishedYes
Event10th International Symposium on SiO2 Advanced Dielectrics and Related Devices, SiO 2014 - Cagliari, Italy
Duration: 16 Jun 201418 Jun 2014

Publication series

NameAIP Conference Proceedings
Volume1624
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference10th International Symposium on SiO2 Advanced Dielectrics and Related Devices, SiO 2014
Country/TerritoryItaly
CityCagliari
Period16/06/1418/06/14

Keywords

  • Ln-complex
  • hybrid materials
  • photoluminescence
  • silica film
  • sol-gel
  • time-resolved spectroscopy

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