Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol

Matthew E. Potter; Mary E. Cholerton; Julija Kezina; Richard Bounds; Marina Carravetta; Maela Manzoli; Enrica Gianotti; Michael Lefenfeld; Robert Raja

doi:10.1021/cs501092b

Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol

Matthew E. Potter
, Mary E. Cholerton
, Julija Kezina
, Richard Bounds
, Marina Carravetta
, Maela Manzoli
, Enrica Gianotti
, Michael Lefenfeld
, Robert Raja

Department of Sustainable Development and Ecological Transition

Research output: Contribution to journal › Article › peer-review

Abstract

Silicoaluminophosphates, SAPO-5 and SAPO-34, differ not only in their pore diameters and structural topology but also in their preferred mechanism of silicon substitution into the framework, which subsequently influences the nature of the acid sites for solid-acid-catalyzed transformations. This study combines ²⁹Si NMR, FTIR, and DFT calculations for probing the nature of the isolated acid sites, thereby affording structure-property correlations, in the low-temperature catalytic dehydration of ethanol to ethylene.

Original language	English
Pages (from-to)	4161-4169
Number of pages	9
Journal	ACS Catalysis
Volume	4
Issue number	11
DOIs	https://doi.org/10.1021/cs501092b
Publication status	Published - 10 Oct 2014

Keywords

SAPO
Si NMR
ethanol dehydration
single-site
solid-acid
structure-activity relationships
synergy

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10.1021/cs501092b

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title = "Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol",

abstract = "Silicoaluminophosphates, SAPO-5 and SAPO-34, differ not only in their pore diameters and structural topology but also in their preferred mechanism of silicon substitution into the framework, which subsequently influences the nature of the acid sites for solid-acid-catalyzed transformations. This study combines 29Si NMR, FTIR, and DFT calculations for probing the nature of the isolated acid sites, thereby affording structure-property correlations, in the low-temperature catalytic dehydration of ethanol to ethylene.",

keywords = "SAPO, Si NMR, ethanol dehydration, single-site, solid-acid, structure-activity relationships, synergy",

author = "Potter, \{Matthew E.\} and Cholerton, \{Mary E.\} and Julija Kezina and Richard Bounds and Marina Carravetta and Maela Manzoli and Enrica Gianotti and Michael Lefenfeld and Robert Raja",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

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doi = "10.1021/cs501092b",

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T1 - Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol

AU - Potter, Matthew E.

AU - Cholerton, Mary E.

AU - Kezina, Julija

AU - Bounds, Richard

AU - Carravetta, Marina

AU - Manzoli, Maela

AU - Gianotti, Enrica

AU - Lefenfeld, Michael

AU - Raja, Robert

PY - 2014/10/10

Y1 - 2014/10/10

N2 - Silicoaluminophosphates, SAPO-5 and SAPO-34, differ not only in their pore diameters and structural topology but also in their preferred mechanism of silicon substitution into the framework, which subsequently influences the nature of the acid sites for solid-acid-catalyzed transformations. This study combines 29Si NMR, FTIR, and DFT calculations for probing the nature of the isolated acid sites, thereby affording structure-property correlations, in the low-temperature catalytic dehydration of ethanol to ethylene.

AB - Silicoaluminophosphates, SAPO-5 and SAPO-34, differ not only in their pore diameters and structural topology but also in their preferred mechanism of silicon substitution into the framework, which subsequently influences the nature of the acid sites for solid-acid-catalyzed transformations. This study combines 29Si NMR, FTIR, and DFT calculations for probing the nature of the isolated acid sites, thereby affording structure-property correlations, in the low-temperature catalytic dehydration of ethanol to ethylene.

KW - SAPO

KW - Si NMR

KW - ethanol dehydration

KW - single-site

KW - solid-acid

KW - structure-activity relationships

KW - synergy

UR - https://www.scopus.com/pages/publications/84910027028

U2 - 10.1021/cs501092b

DO - 10.1021/cs501092b

M3 - Article

SN - 2155-5435

VL - 4

SP - 4161

EP - 4169

JO - ACS Catalysis

JF - ACS Catalysis

IS - 11

ER -

Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol

Abstract

Keywords

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