Reactions of Fe3(CO)12 with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of...

Federica Bertolotti; Giuliana Gervasio; Domenica Marabello; Enrico Sappa; Andrea Secco

doi:10.1016/j.jorganchem.2008.04.045

Reactions of Fe₃(CO)₁₂ with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of...

Federica Bertolotti
, Giuliana Gervasio
, Domenica Marabello
, Enrico Sappa
, Andrea Secco

Research output: Contribution to journal › Article › peer-review

Abstract

Title full: Reactions of Fe₃(CO)₁₂ with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of Fe₂(CO)₆(μ-CO)(μ-η²-[HCC {{double bond, long}C(CH₃)₂}C({double bond, long}O)(OCH₃)]) and of (μ-H)Fe₃(CO)₉(μ₃-η³-[H₃CCC(CH₂)(CH₂)CO]). The reactions of Fe₃(CO)₁₂ with 2-methyl-3-butyn-2-ol and 3-pentyn-1-ol in CH₃OH/KOH solution lead, respectively, to the binuclear complex Fe₂(CO)₆(μ-CO)(μ-η²-[HCC{{dou ble bond, long}C(CH₃)₂}C({double bond, long}O)(OCH₃)]) (as the main product) and to the closed trinuclear hydridic complex (μ-H)Fe₃(CO)₉(μ₃-η³-[H₃CCC(CH₂) (CH₂)CO]) (as the unique product). The oxygenated ligands of these complexes are formed, respectively, by coupling of a formerly coordinated CO with a methoxy group and by coupling of a formerly coordinated CO with a deoxygenated alkynic residual.

Original language	English
Pages (from-to)	2673-2678
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	16
DOIs	https://doi.org/10.1016/j.jorganchem.2008.04.045
Publication status	Published - 1 Aug 2008
Externally published	Yes

Keywords

Alkynols
Coupling of CO with organic fragments
Iron carbonyls
Oxygenated ligands
X-ray structures

Access to Document

10.1016/j.jorganchem.2008.04.045

Cite this

@article{12e90d1623d74b05a7bacbe0dc07699d,

title = "Reactions of Fe3(CO)12 with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of...",

abstract = "Title full: Reactions of Fe3(CO)12 with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of Fe2(CO)6(μ-CO)(μ-η2-[HCC \{\{double bond, long\}C(CH3)2\}C(\{double bond, long\}O)(OCH3)]) and of (μ-H)Fe3(CO)9(μ3-η 3-[H3CCC(CH2)(CH2)CO]). The reactions of Fe3(CO)12 with 2-methyl-3-butyn-2-ol and 3-pentyn-1-ol in CH3OH/KOH solution lead, respectively, to the binuclear complex Fe2(CO)6(μ-CO)(μ-η2-[HCC\{\{dou ble bond, long\}C(CH3)2\}C(\{double bond, long\}O)(OCH3)]) (as the main product) and to the closed trinuclear hydridic complex (μ-H)Fe3(CO)9(μ3-η3 -[H3CCC(CH2) (CH2)CO]) (as the unique product). The oxygenated ligands of these complexes are formed, respectively, by coupling of a formerly coordinated CO with a methoxy group and by coupling of a formerly coordinated CO with a deoxygenated alkynic residual.",

keywords = "Alkynols, Coupling of CO with organic fragments, Iron carbonyls, Oxygenated ligands, X-ray structures",

author = "Federica Bertolotti and Giuliana Gervasio and Domenica Marabello and Enrico Sappa and Andrea Secco",

note = "Funding Information: Financial support to this work was obtained from MIUR (Rome) and Universit{\`a} del Piemonte Orientale as PRIN 2007. Appendix A ",

year = "2008",

month = aug,

day = "1",

doi = "10.1016/j.jorganchem.2008.04.045",

language = "English",

volume = "693",

pages = "2673--2678",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "16",

}

TY - JOUR

T1 - Reactions of Fe3(CO)12 with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions

T2 - The crystal structures of...

AU - Bertolotti, Federica

AU - Gervasio, Giuliana

AU - Marabello, Domenica

AU - Sappa, Enrico

AU - Secco, Andrea

N1 - Funding Information: Financial support to this work was obtained from MIUR (Rome) and Università del Piemonte Orientale as PRIN 2007. Appendix A

PY - 2008/8/1

Y1 - 2008/8/1

N2 - Title full: Reactions of Fe3(CO)12 with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of Fe2(CO)6(μ-CO)(μ-η2-[HCC {{double bond, long}C(CH3)2}C({double bond, long}O)(OCH3)]) and of (μ-H)Fe3(CO)9(μ3-η 3-[H3CCC(CH2)(CH2)CO]). The reactions of Fe3(CO)12 with 2-methyl-3-butyn-2-ol and 3-pentyn-1-ol in CH3OH/KOH solution lead, respectively, to the binuclear complex Fe2(CO)6(μ-CO)(μ-η2-[HCC{{dou ble bond, long}C(CH3)2}C({double bond, long}O)(OCH3)]) (as the main product) and to the closed trinuclear hydridic complex (μ-H)Fe3(CO)9(μ3-η3 -[H3CCC(CH2) (CH2)CO]) (as the unique product). The oxygenated ligands of these complexes are formed, respectively, by coupling of a formerly coordinated CO with a methoxy group and by coupling of a formerly coordinated CO with a deoxygenated alkynic residual.

AB - Title full: Reactions of Fe3(CO)12 with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of Fe2(CO)6(μ-CO)(μ-η2-[HCC {{double bond, long}C(CH3)2}C({double bond, long}O)(OCH3)]) and of (μ-H)Fe3(CO)9(μ3-η 3-[H3CCC(CH2)(CH2)CO]). The reactions of Fe3(CO)12 with 2-methyl-3-butyn-2-ol and 3-pentyn-1-ol in CH3OH/KOH solution lead, respectively, to the binuclear complex Fe2(CO)6(μ-CO)(μ-η2-[HCC{{dou ble bond, long}C(CH3)2}C({double bond, long}O)(OCH3)]) (as the main product) and to the closed trinuclear hydridic complex (μ-H)Fe3(CO)9(μ3-η3 -[H3CCC(CH2) (CH2)CO]) (as the unique product). The oxygenated ligands of these complexes are formed, respectively, by coupling of a formerly coordinated CO with a methoxy group and by coupling of a formerly coordinated CO with a deoxygenated alkynic residual.

KW - Alkynols

KW - Coupling of CO with organic fragments

KW - Iron carbonyls

KW - Oxygenated ligands

KW - X-ray structures

UR - https://www.scopus.com/pages/publications/47149102331

U2 - 10.1016/j.jorganchem.2008.04.045

DO - 10.1016/j.jorganchem.2008.04.045

M3 - Article

SN - 0022-328X

VL - 693

SP - 2673

EP - 2678

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 16

ER -

Reactions of Fe₃(CO)₁₂ with 2-methyl-3-butyn-1-ol and 3-pentyn-1-ol under basic methanolic conditions: The crystal structures of...

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this