Quasienantiomeric levoglucosenone and isolevoglucosenone allow the parallel kinetic resolution of a racemic nitrone

F CARDONA; DANIELA LALLI; C FAGGI; A GOTI; A BRANDI

Quasienantiomeric levoglucosenone and isolevoglucosenone allow the parallel kinetic resolution of a racemic nitrone

F CARDONA, DANIELA LALLI, C FAGGI, A GOTI, A BRANDI

Department of Science and Technological Innovation

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) Cycloadditions of chiral pyrroline N-oxides to levoglucose-none (1) and isolevoglucosenone (2) proceed with a high level of double asymmetric induction. Partial kinetic resolutions (KR) of both enantiomers of a racemic nitrone 3 were achieved, and a parallel kinetic resolution (PKR) experiment allowed the stereoselective divergent synthesis of two quasienantiomeric imino-C-disaccharide precursors.

Original language	English
Pages (from-to)	1999-2002
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	73
Publication status	Published - 2008

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@article{3066bbd2d8d14e3097ec4afb3699442c,

title = "Quasienantiomeric levoglucosenone and isolevoglucosenone allow the parallel kinetic resolution of a racemic nitrone",

abstract = "(Chemical Equation Presented) Cycloadditions of chiral pyrroline N-oxides to levoglucose-none (1) and isolevoglucosenone (2) proceed with a high level of double asymmetric induction. Partial kinetic resolutions (KR) of both enantiomers of a racemic nitrone 3 were achieved, and a parallel kinetic resolution (PKR) experiment allowed the stereoselective divergent synthesis of two quasienantiomeric imino-C-disaccharide precursors.",

author = "F CARDONA and DANIELA LALLI and C FAGGI and A GOTI and A BRANDI",

year = "2008",

language = "English",

volume = "73",

pages = "1999--2002",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Quasienantiomeric levoglucosenone and isolevoglucosenone allow the parallel kinetic resolution of a racemic nitrone

AU - CARDONA, F

AU - LALLI, DANIELA

AU - FAGGI, C

AU - GOTI, A

AU - BRANDI, A

PY - 2008

Y1 - 2008

N2 - (Chemical Equation Presented) Cycloadditions of chiral pyrroline N-oxides to levoglucose-none (1) and isolevoglucosenone (2) proceed with a high level of double asymmetric induction. Partial kinetic resolutions (KR) of both enantiomers of a racemic nitrone 3 were achieved, and a parallel kinetic resolution (PKR) experiment allowed the stereoselective divergent synthesis of two quasienantiomeric imino-C-disaccharide precursors.

AB - (Chemical Equation Presented) Cycloadditions of chiral pyrroline N-oxides to levoglucose-none (1) and isolevoglucosenone (2) proceed with a high level of double asymmetric induction. Partial kinetic resolutions (KR) of both enantiomers of a racemic nitrone 3 were achieved, and a parallel kinetic resolution (PKR) experiment allowed the stereoselective divergent synthesis of two quasienantiomeric imino-C-disaccharide precursors.

UR - https://iris.uniupo.it/handle/11579/106922

M3 - Article

SN - 0022-3263

VL - 73

SP - 1999

EP - 2002

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

ER -

Quasienantiomeric levoglucosenone and isolevoglucosenone allow the parallel kinetic resolution of a racemic nitrone

Abstract

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