Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

Guido Saracco; Svetoslava Vankova; Cristina Pagliano; Barbara Bonelli; Edoardo Garrone

doi:10.1039/c3cp54896a

Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

Guido Saracco
, Svetoslava Vankova
, Cristina Pagliano
, Barbara Bonelli
, Edoardo Garrone

Research output: Contribution to journal › Article › peer-review

Abstract

Outer Co(ii) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component. This journal is

Original language	English
Pages (from-to)	6139-6145
Number of pages	7
Journal	Physical Chemistry Chemical Physics
Volume	16
Issue number	13
DOIs	https://doi.org/10.1039/c3cp54896a
Publication status	Published - 7 Apr 2014
Externally published	Yes

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abstract = "Outer Co(ii) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component. This journal is",

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AU - Saracco, Guido

AU - Vankova, Svetoslava

AU - Pagliano, Cristina

AU - Bonelli, Barbara

AU - Garrone, Edoardo

PY - 2014/4/7

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AB - Outer Co(ii) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component. This journal is

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Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

Abstract

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