Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)

S AIME; Mauro BOTTA; R GOBETTO; Domenico OSELLA

doi:10.1039/dt9880000791

Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)

S AIME, Mauro BOTTA, R GOBETTO, Domenico OSELLA

Department of Science and Technological Innovation

Research output: Contribution to journal › Article › peer-review

Abstract

The combined use of ¹³C and ¹⁷O spin-lattice relaxation times for co-ordinated carbonyl ligands in [M₃(CO)₁₂] clusters (M = Fe, Ru, or Os) allows the determination of ¹⁷O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.

Original language	English
Pages (from-to)	791-792
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/dt9880000791
Publication status	Published - 1988

Access to Document

10.1039/dt9880000791

http://hdl.handle.net/11579/31230

Cite this

@article{fcc37ab1a75e4f20b75f639d56a67e74,

title = "Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)",

abstract = "The combined use of 13C and 17O spin-lattice relaxation times for co-ordinated carbonyl ligands in [M3(CO)12] clusters (M = Fe, Ru, or Os) allows the determination of 17O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.",

author = "S AIME and Mauro BOTTA and R GOBETTO and Domenico OSELLA",

year = "1988",

doi = "10.1039/dt9880000791",

language = "English",

pages = "791--792",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)

AU - AIME, S

AU - BOTTA, Mauro

AU - GOBETTO, R

AU - OSELLA, Domenico

PY - 1988

Y1 - 1988

N2 - The combined use of 13C and 17O spin-lattice relaxation times for co-ordinated carbonyl ligands in [M3(CO)12] clusters (M = Fe, Ru, or Os) allows the determination of 17O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.

AB - The combined use of 13C and 17O spin-lattice relaxation times for co-ordinated carbonyl ligands in [M3(CO)12] clusters (M = Fe, Ru, or Os) allows the determination of 17O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.

UR - https://iris.uniupo.it/handle/11579/31230

U2 - 10.1039/dt9880000791

DO - 10.1039/dt9880000791

M3 - Article

SN - 0300-9246

SP - 791

EP - 792

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 3

ER -

Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this