Nitrile functionalised pendant-arm derivatives of aza- and mixed donor macrocyclic ligands as new building blocks for inorganic crystal engineering

Lorenzo Tei; Alexander J. Blake; Paul A. Cooke; Claudia Caltagirone; Francesco Demartin; Vito Lippolis; Francesca Morale; Claire Wilson; Martin Schröder

doi:10.1039/b110134j

Nitrile functionalised pendant-arm derivatives of aza- and mixed donor macrocyclic ligands as new building blocks for inorganic crystal engineering

Lorenzo Tei, Alexander J. Blake, Paul A. Cooke, Claudia Caltagirone, Francesco Demartin, Vito Lippolis, Francesca Morale, Claire Wilson, Martin Schröder

Research output: Contribution to journal › Article › peer-review

Abstract

A range of nitrile-functionalised pendant arm derivatives of [9]aneN₃, [9]aneN₂S, [9]aneNS₂, [12]aneNS₂O and [15]aneO₂N₃ have been prepared: L¹ = 1,4,7-tris(cyanomethyl)-1,4,7-triazacyclononane, L² = 1,4,7-tris-(2-cyanoethyl)-1,4,7-triazacyclononane, L³ = 1,2-bis[4,7-bis(2-cyanoethyl)-1,4,7-triazacyclonon-lyl]ethane, L⁴ = 4,7-bis(2-cyanoethyl)-1-thia-4,7-diazacyclononane, L⁵ = 7-(2-cyanoethyl)-7-aza-1,4-dithiacyclononane, L⁶ = 1-(2-cyanoethyl)-1-aza-4,10-dithia-7-oxacyclododecane, L⁷ = 1,4,7-tris(cyanomethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane, L⁸ = 1,4,7-tris(cyanoethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane. Reaction of these ligands with Ag^I salts affords a range of complex products, the structures of which vary according to the type, number and length of the pendant arms. The synthesis and structures of {[Ag(L¹)]PF₆}_∞, {[Ag₂(L²)₂][BF₄]₂} _∞, {[Ag₂(L³)][PF₆]₂} _∞, [Ag₂(L⁴)₂][BF₄]₂, {[Ag(L⁵)]BF₄}_∞, [Ag₂(L⁶)₂][BF₄]₂, {[Ag(L⁷)]BF₄}_∞ and [Ag(L⁸)]PF₂O₂ are reported.

Original language	English
Pages (from-to)	1662-1670
Number of pages	9
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	8
DOIs	https://doi.org/10.1039/b110134j
Publication status	Published - 2002
Externally published	Yes

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Tei, L., Blake, A. J., Cooke, P. A., Caltagirone, C., Demartin, F., Lippolis, V., Morale, F., Wilson, C., & Schröder, M. (2002). Nitrile functionalised pendant-arm derivatives of aza- and mixed donor macrocyclic ligands as new building blocks for inorganic crystal engineering. Journal of the Chemical Society. Dalton Transactions, (8), 1662-1670. https://doi.org/10.1039/b110134j

@article{6b03ad28453244c19fad97849d9dd8b2,

title = "Nitrile functionalised pendant-arm derivatives of aza- and mixed donor macrocyclic ligands as new building blocks for inorganic crystal engineering",

abstract = "A range of nitrile-functionalised pendant arm derivatives of [9]aneN3, [9]aneN2S, [9]aneNS2, [12]aneNS2O and [15]aneO2N3 have been prepared: L1 = 1,4,7-tris(cyanomethyl)-1,4,7-triazacyclononane, L2 = 1,4,7-tris-(2-cyanoethyl)-1,4,7-triazacyclononane, L3 = 1,2-bis[4,7-bis(2-cyanoethyl)-1,4,7-triazacyclonon-lyl]ethane, L4 = 4,7-bis(2-cyanoethyl)-1-thia-4,7-diazacyclononane, L5 = 7-(2-cyanoethyl)-7-aza-1,4-dithiacyclononane, L6 = 1-(2-cyanoethyl)-1-aza-4,10-dithia-7-oxacyclododecane, L7 = 1,4,7-tris(cyanomethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane, L8 = 1,4,7-tris(cyanoethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane. Reaction of these ligands with AgI salts affords a range of complex products, the structures of which vary according to the type, number and length of the pendant arms. The synthesis and structures of {[Ag(L1)]PF6}∞, {[Ag2(L2)2][BF4]2} ∞, {[Ag2(L3)][PF6]2} ∞, [Ag2(L4)2][BF4]2, {[Ag(L5)]BF4}∞, [Ag2(L6)2][BF4]2, {[Ag(L7)]BF4}∞ and [Ag(L8)]PF2O2 are reported.",

author = "Lorenzo Tei and Blake, {Alexander J.} and Cooke, {Paul A.} and Claudia Caltagirone and Francesco Demartin and Vito Lippolis and Francesca Morale and Claire Wilson and Martin Schr{\"o}der",

year = "2002",

doi = "10.1039/b110134j",

language = "English",

pages = "1662--1670",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "8",

}

Tei, L, Blake, AJ, Cooke, PA, Caltagirone, C, Demartin, F, Lippolis, V, Morale, F, Wilson, C & Schröder, M 2002, 'Nitrile functionalised pendant-arm derivatives of aza- and mixed donor macrocyclic ligands as new building blocks for inorganic crystal engineering', Journal of the Chemical Society. Dalton Transactions, no. 8, pp. 1662-1670. https://doi.org/10.1039/b110134j

TY - JOUR

T1 - Nitrile functionalised pendant-arm derivatives of aza- and mixed donor macrocyclic ligands as new building blocks for inorganic crystal engineering

AU - Tei, Lorenzo

AU - Blake, Alexander J.

AU - Cooke, Paul A.

AU - Caltagirone, Claudia

AU - Demartin, Francesco

AU - Lippolis, Vito

AU - Morale, Francesca

AU - Wilson, Claire

AU - Schröder, Martin

PY - 2002

Y1 - 2002

N2 - A range of nitrile-functionalised pendant arm derivatives of [9]aneN3, [9]aneN2S, [9]aneNS2, [12]aneNS2O and [15]aneO2N3 have been prepared: L1 = 1,4,7-tris(cyanomethyl)-1,4,7-triazacyclononane, L2 = 1,4,7-tris-(2-cyanoethyl)-1,4,7-triazacyclononane, L3 = 1,2-bis[4,7-bis(2-cyanoethyl)-1,4,7-triazacyclonon-lyl]ethane, L4 = 4,7-bis(2-cyanoethyl)-1-thia-4,7-diazacyclononane, L5 = 7-(2-cyanoethyl)-7-aza-1,4-dithiacyclononane, L6 = 1-(2-cyanoethyl)-1-aza-4,10-dithia-7-oxacyclododecane, L7 = 1,4,7-tris(cyanomethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane, L8 = 1,4,7-tris(cyanoethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane. Reaction of these ligands with AgI salts affords a range of complex products, the structures of which vary according to the type, number and length of the pendant arms. The synthesis and structures of {[Ag(L1)]PF6}∞, {[Ag2(L2)2][BF4]2} ∞, {[Ag2(L3)][PF6]2} ∞, [Ag2(L4)2][BF4]2, {[Ag(L5)]BF4}∞, [Ag2(L6)2][BF4]2, {[Ag(L7)]BF4}∞ and [Ag(L8)]PF2O2 are reported.

AB - A range of nitrile-functionalised pendant arm derivatives of [9]aneN3, [9]aneN2S, [9]aneNS2, [12]aneNS2O and [15]aneO2N3 have been prepared: L1 = 1,4,7-tris(cyanomethyl)-1,4,7-triazacyclononane, L2 = 1,4,7-tris-(2-cyanoethyl)-1,4,7-triazacyclononane, L3 = 1,2-bis[4,7-bis(2-cyanoethyl)-1,4,7-triazacyclonon-lyl]ethane, L4 = 4,7-bis(2-cyanoethyl)-1-thia-4,7-diazacyclononane, L5 = 7-(2-cyanoethyl)-7-aza-1,4-dithiacyclononane, L6 = 1-(2-cyanoethyl)-1-aza-4,10-dithia-7-oxacyclododecane, L7 = 1,4,7-tris(cyanomethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane, L8 = 1,4,7-tris(cyanoethyl)-1,4,7-triaza-10,13-dioxacyclopentadecane. Reaction of these ligands with AgI salts affords a range of complex products, the structures of which vary according to the type, number and length of the pendant arms. The synthesis and structures of {[Ag(L1)]PF6}∞, {[Ag2(L2)2][BF4]2} ∞, {[Ag2(L3)][PF6]2} ∞, [Ag2(L4)2][BF4]2, {[Ag(L5)]BF4}∞, [Ag2(L6)2][BF4]2, {[Ag(L7)]BF4}∞ and [Ag(L8)]PF2O2 are reported.

UR - http://www.scopus.com/inward/record.url?scp=0036009965&partnerID=8YFLogxK

U2 - 10.1039/b110134j

DO - 10.1039/b110134j

M3 - Article

SN - 1470-479X

SP - 1662

EP - 1670

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 8

ER -

Nitrile functionalised pendant-arm derivatives of aza- and mixed donor macrocyclic ligands as new building blocks for inorganic crystal engineering

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