Metal-metal and metal-ligand vibrational interaction in compounds of the Fe3EE′(CO)9 (E, E′ = S, Se, Te) series and the low-frequency vibrational spectra of CO2FeS(CO)9 and Os3S2(CO)9

S. F.A. Kettle; E. Diana; R. Rossetti; E. Boccaleri; U. A. Jayasooryia; P. L. Stanghellini

doi:10.1021/ic991254s

Metal-metal and metal-ligand vibrational interaction in compounds of the Fe₃EE′(CO)₉ (E, E′ = S, Se, Te) series and the low-frequency vibrational spectra of CO₂FeS(CO)₉ and Os₃S₂(CO)₉

S. F.A. Kettle
, E. Diana
, R. Rossetti
, E. Boccaleri
, U. A. Jayasooryia
, P. L. Stanghellini

Research output: Contribution to journal › Article › peer-review

Abstract

The infrared and Raman spectra of the title compounds in the ca. 400-150 cm^-1 region are reported. For the first time, detailed assignments are given for all of the features in this region for the first series of compounds. An attempt is made to extend to all of the modes the plastic cluster model of vibrational analysis, which is normally species applied only to ν(M - M) vibrations. While mixing occurs between ν(Fe - Fe) and ν(Fe - E), containing Te posed particular problems; the reasons for this are discussed and give new insights into the plastic cluster model itself.

Original language	English
Pages (from-to)	5690-5696
Number of pages	7
Journal	Inorganic Chemistry
Volume	39
Issue number	25
DOIs	https://doi.org/10.1021/ic991254s
Publication status	Published - 11 Dec 2000
Externally published	Yes

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10.1021/ic991254s

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Kettle, S. F. A., Diana, E., Rossetti, R., Boccaleri, E., Jayasooryia, U. A., & Stanghellini, P. L. (2000). Metal-metal and metal-ligand vibrational interaction in compounds of the Fe₃EE′(CO)₉ (E, E′ = S, Se, Te) series and the low-frequency vibrational spectra of CO₂FeS(CO)₉ and Os₃S₂(CO)₉. Inorganic Chemistry, 39(25), 5690-5696. https://doi.org/10.1021/ic991254s

@article{50ac89e6aed14a869432e201e661f9ae,

title = "Metal-metal and metal-ligand vibrational interaction in compounds of the Fe3EE′(CO)9 (E, E′ = S, Se, Te) series and the low-frequency vibrational spectra of CO2FeS(CO)9 and Os3S2(CO)9",

abstract = "The infrared and Raman spectra of the title compounds in the ca. 400-150 cm-1 region are reported. For the first time, detailed assignments are given for all of the features in this region for the first series of compounds. An attempt is made to extend to all of the modes the plastic cluster model of vibrational analysis, which is normally species applied only to ν(M - M) vibrations. While mixing occurs between ν(Fe - Fe) and ν(Fe - E), containing Te posed particular problems; the reasons for this are discussed and give new insights into the plastic cluster model itself.",

author = "Kettle, \{S. F.A.\} and E. Diana and R. Rossetti and E. Boccaleri and Jayasooryia, \{U. A.\} and Stanghellini, \{P. L.\}",

year = "2000",

month = dec,

day = "11",

doi = "10.1021/ic991254s",

language = "English",

volume = "39",

pages = "5690--5696",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "25",

}

Metal-metal and metal-ligand vibrational interaction in compounds of the Fe₃EE′(CO)₉ (E, E′ = S, Se, Te) series and the low-frequency vibrational spectra of CO₂FeS(CO)₉ and Os₃S₂(CO)₉. / Kettle, S. F.A.; Diana, E.; Rossetti, R. et al.
In: Inorganic Chemistry, Vol. 39, No. 25, 11.12.2000, p. 5690-5696.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal-metal and metal-ligand vibrational interaction in compounds of the Fe3EE′(CO)9 (E, E′ = S, Se, Te) series and the low-frequency vibrational spectra of CO2FeS(CO)9 and Os3S2(CO)9

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Rossetti, R.

AU - Boccaleri, E.

AU - Jayasooryia, U. A.

AU - Stanghellini, P. L.

PY - 2000/12/11

Y1 - 2000/12/11

N2 - The infrared and Raman spectra of the title compounds in the ca. 400-150 cm-1 region are reported. For the first time, detailed assignments are given for all of the features in this region for the first series of compounds. An attempt is made to extend to all of the modes the plastic cluster model of vibrational analysis, which is normally species applied only to ν(M - M) vibrations. While mixing occurs between ν(Fe - Fe) and ν(Fe - E), containing Te posed particular problems; the reasons for this are discussed and give new insights into the plastic cluster model itself.

AB - The infrared and Raman spectra of the title compounds in the ca. 400-150 cm-1 region are reported. For the first time, detailed assignments are given for all of the features in this region for the first series of compounds. An attempt is made to extend to all of the modes the plastic cluster model of vibrational analysis, which is normally species applied only to ν(M - M) vibrations. While mixing occurs between ν(Fe - Fe) and ν(Fe - E), containing Te posed particular problems; the reasons for this are discussed and give new insights into the plastic cluster model itself.

UR - https://www.scopus.com/pages/publications/0034638882

U2 - 10.1021/ic991254s

DO - 10.1021/ic991254s

M3 - Article

SN - 0020-1669

VL - 39

SP - 5690

EP - 5696

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 25

ER -

Metal-metal and metal-ligand vibrational interaction in compounds of the Fe₃EE′(CO)₉ (E, E′ = S, Se, Te) series and the low-frequency vibrational spectra of CO₂FeS(CO)₉ and Os₃S₂(CO)₉

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