liquid-Crystalline side-chain polyacrylates containing chiral sulfoxide substituents

E. Chiellini; G. Galli; A. S. Angeloni; M. Laus; S. Melone; O. Francescangeli

doi:10.1080/10587259508033642

liquid-Crystalline side-chain polyacrylates containing chiral sulfoxide substituents

E. Chiellini
, G. Galli
, A. S. Angeloni
, M. Laus
, S. Melone
, O. Francescangeli

Department of Science and Technological Innovation

Research output: Contribution to journal › Article › peer-review

Abstract

A series of side-chain polyacrylates containing chiral, optically active sulfoxide substituents was prepared by the enantioselective oxidation of the corresponding prochiral polyacrylates containing prochiral sulfide substituents. A chiral sulfonyloxaziridine was used as the oxidant. The chemical modification was selective from chemical and stereochemical standpoints. The resulting polymers formed chiral nematic and/or smectic phases with a slightly decreased propensity to give stable and persistent mesophases with respect to the parent sulfide containing polymers.

Original language	English
Pages (from-to)	189-196
Number of pages	8
Journal	Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals
Volume	266
Issue number	1
DOIs	https://doi.org/10.1080/10587259508033642
Publication status	Published - Jun 1995

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title = "liquid-Crystalline side-chain polyacrylates containing chiral sulfoxide substituents",

abstract = "A series of side-chain polyacrylates containing chiral, optically active sulfoxide substituents was prepared by the enantioselective oxidation of the corresponding prochiral polyacrylates containing prochiral sulfide substituents. A chiral sulfonyloxaziridine was used as the oxidant. The chemical modification was selective from chemical and stereochemical standpoints. The resulting polymers formed chiral nematic and/or smectic phases with a slightly decreased propensity to give stable and persistent mesophases with respect to the parent sulfide containing polymers.",

author = "E. Chiellini and G. Galli and Angeloni, \{A. S.\} and M. Laus and S. Melone and O. Francescangeli",

note = "Funding Information: Acknowledgment. This work was', performed with the support from the Progetto Finalizzato CNR Chimica Fine II.",

year = "1995",

month = jun,

doi = "10.1080/10587259508033642",

language = "English",

volume = "266",

pages = "189--196",

journal = "Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals",

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number = "1",

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T1 - liquid-Crystalline side-chain polyacrylates containing chiral sulfoxide substituents

AU - Chiellini, E.

AU - Galli, G.

AU - Angeloni, A. S.

AU - Laus, M.

AU - Melone, S.

AU - Francescangeli, O.

N1 - Funding Information: Acknowledgment. This work was', performed with the support from the Progetto Finalizzato CNR Chimica Fine II.

PY - 1995/6

Y1 - 1995/6

N2 - A series of side-chain polyacrylates containing chiral, optically active sulfoxide substituents was prepared by the enantioselective oxidation of the corresponding prochiral polyacrylates containing prochiral sulfide substituents. A chiral sulfonyloxaziridine was used as the oxidant. The chemical modification was selective from chemical and stereochemical standpoints. The resulting polymers formed chiral nematic and/or smectic phases with a slightly decreased propensity to give stable and persistent mesophases with respect to the parent sulfide containing polymers.

AB - A series of side-chain polyacrylates containing chiral, optically active sulfoxide substituents was prepared by the enantioselective oxidation of the corresponding prochiral polyacrylates containing prochiral sulfide substituents. A chiral sulfonyloxaziridine was used as the oxidant. The chemical modification was selective from chemical and stereochemical standpoints. The resulting polymers formed chiral nematic and/or smectic phases with a slightly decreased propensity to give stable and persistent mesophases with respect to the parent sulfide containing polymers.

UR - https://www.scopus.com/pages/publications/84972839742

U2 - 10.1080/10587259508033642

DO - 10.1080/10587259508033642

M3 - Article

SN - 1058-725X

VL - 266

SP - 189

EP - 196

JO - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

IS - 1

ER -

liquid-Crystalline side-chain polyacrylates containing chiral sulfoxide substituents

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