Ligand Dynamics in H2Os3(CO)10 and H2Os3(CO)10L

S. Aime; D. Osella; L. Milone; E. Rosenberg

doi:10.1016/S0022-328X(00)93960-3

Ligand Dynamics in H₂Os₃(CO)₁₀ and H₂Os₃(CO)₁₀L

S. Aime
, D. Osella
, L. Milone
, E. Rosenberg

Research output: Contribution to journal › Article › peer-review

Abstract

The variable temperature ¹³C NMR spectra of H₂Os₃(CO)₁₀ and H₂Os₃(CO)₁₀L (L P(C₆H₅)₃, P(O-i_C₃H₇)s3) and P(i_C₃H₇)₃) have been recorded and the results interpreted in terms of a localized exchange process involving concerted motion of the hydride and the carbonyl ligands. Taken along with previously reported variable temperature ¹H NMR data the results provide a complete picture of the ligand dynamics in these systems.

Original language	English
Pages (from-to)	207-213
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	213
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)93960-3
Publication status	Published - 16 Jun 1981
Externally published	Yes

Access to Document

10.1016/S0022-328X(00)93960-3

Cite this

@article{654dfa775a50454198f5f75eebd216ae,

title = "Ligand Dynamics in H2Os3(CO)10 and H2Os3(CO)10L",

abstract = "The variable temperature 13C NMR spectra of H2Os3(CO)10 and H2Os3(CO)10L (L P(C6H5)3, P(O-i\_C3H7)s3) and P(i\_C3H7)3) have been recorded and the results interpreted in terms of a localized exchange process involving concerted motion of the hydride and the carbonyl ligands. Taken along with previously reported variable temperature 1H NMR data the results provide a complete picture of the ligand dynamics in these systems.",

author = "S. Aime and D. Osella and L. Milone and E. Rosenberg",

note = "Funding Information: We thank Johnson and Matthey Co., London, for a loan of 0\textasciitilde{}0\textasciitilde{} (L-M.). We also acknowledge support from NATO (L.M. and E-R., grant 1649/79), C.N.R. (S-A., Grant 79.02343.64) and PRF (E-R., Grant 9631 G4).",

year = "1981",

month = jun,

day = "16",

doi = "10.1016/S0022-328X(00)93960-3",

language = "English",

volume = "213",

pages = "207--213",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Ligand Dynamics in H2Os3(CO)10 and H2Os3(CO)10L

AU - Aime, S.

AU - Osella, D.

AU - Milone, L.

AU - Rosenberg, E.

N1 - Funding Information: We thank Johnson and Matthey Co., London, for a loan of 0~0~ (L-M.). We also acknowledge support from NATO (L.M. and E-R., grant 1649/79), C.N.R. (S-A., Grant 79.02343.64) and PRF (E-R., Grant 9631 G4).

PY - 1981/6/16

Y1 - 1981/6/16

N2 - The variable temperature 13C NMR spectra of H2Os3(CO)10 and H2Os3(CO)10L (L P(C6H5)3, P(O-i_C3H7)s3) and P(i_C3H7)3) have been recorded and the results interpreted in terms of a localized exchange process involving concerted motion of the hydride and the carbonyl ligands. Taken along with previously reported variable temperature 1H NMR data the results provide a complete picture of the ligand dynamics in these systems.

AB - The variable temperature 13C NMR spectra of H2Os3(CO)10 and H2Os3(CO)10L (L P(C6H5)3, P(O-i_C3H7)s3) and P(i_C3H7)3) have been recorded and the results interpreted in terms of a localized exchange process involving concerted motion of the hydride and the carbonyl ligands. Taken along with previously reported variable temperature 1H NMR data the results provide a complete picture of the ligand dynamics in these systems.

UR - https://www.scopus.com/pages/publications/0001302617

U2 - 10.1016/S0022-328X(00)93960-3

DO - 10.1016/S0022-328X(00)93960-3

M3 - Article

SN - 0022-328X

VL - 213

SP - 207

EP - 213

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Ligand Dynamics in H₂Os₃(CO)₁₀ and H₂Os₃(CO)₁₀L

Abstract

Access to Document

Other files and links

Fingerprint

Cite this