Lanthanide(III) Complexes with a Podand Schiff Base Containing a N4O3 Coordination Site

U. CASELLATO; S. TAMBURINI; P. T.O.M.A.S.I.N. P. A. VIGATO; Mauro BOTTA

Lanthanide(III) Complexes with a Podand Schiff Base Containing a N4O3 Coordination Site

U. CASELLATO
, S. TAMBURINI
, P. T.O.M.A.S.I.N. P. A. VIGATO
, Mauro BOTTA

Department of Science and Technological Innovation

Research output: Contribution to journal › Article

Abstract

New lanthanide complexes [Ln(L) (dmf)]₂ with a podand Schiff base ligand H₃L have been prepared by [3 + 1] condensation of 2,6-diformyl-4-chlorophenol and tris-(2-aminoethyl)amine in the presence of Ln(Cl)₃·nH₂O (Ln=La, Gd and Dy) and NEt₃. The lanthanide (III) ions coordinate into the inner N₄O₃ chamber of the ligand bearing three free carbonyl groups which may be involved in further functionalization.

Original language	English
Pages (from-to)	143-145
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	247
Publication status	Published - 1996

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title = "Lanthanide(III) Complexes with a Podand Schiff Base Containing a N4O3 Coordination Site",

abstract = "New lanthanide complexes [Ln(L) (dmf)]2 with a podand Schiff base ligand H3L have been prepared by [3 + 1] condensation of 2,6-diformyl-4-chlorophenol and tris-(2-aminoethyl)amine in the presence of Ln(Cl)3·nH2O (Ln=La, Gd and Dy) and NEt3. The lanthanide (III) ions coordinate into the inner N4O3 chamber of the ligand bearing three free carbonyl groups which may be involved in further functionalization.",

author = "U. CASELLATO and S. TAMBURINI and VIGATO, \{P. T.O.M.A.S.I.N. P. A.\} and Mauro BOTTA",

year = "1996",

language = "English",

volume = "247",

pages = "143--145",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Lanthanide(III) Complexes with a Podand Schiff Base Containing a N4O3 Coordination Site

AU - CASELLATO, U.

AU - TAMBURINI, S.

AU - VIGATO, P. T.O.M.A.S.I.N. P. A.

AU - BOTTA, Mauro

PY - 1996

Y1 - 1996

N2 - New lanthanide complexes [Ln(L) (dmf)]2 with a podand Schiff base ligand H3L have been prepared by [3 + 1] condensation of 2,6-diformyl-4-chlorophenol and tris-(2-aminoethyl)amine in the presence of Ln(Cl)3·nH2O (Ln=La, Gd and Dy) and NEt3. The lanthanide (III) ions coordinate into the inner N4O3 chamber of the ligand bearing three free carbonyl groups which may be involved in further functionalization.

AB - New lanthanide complexes [Ln(L) (dmf)]2 with a podand Schiff base ligand H3L have been prepared by [3 + 1] condensation of 2,6-diformyl-4-chlorophenol and tris-(2-aminoethyl)amine in the presence of Ln(Cl)3·nH2O (Ln=La, Gd and Dy) and NEt3. The lanthanide (III) ions coordinate into the inner N4O3 chamber of the ligand bearing three free carbonyl groups which may be involved in further functionalization.

UR - https://iris.uniupo.it/handle/11579/3657

M3 - Article

SN - 0020-1693

VL - 247

SP - 143

EP - 145

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Lanthanide(III) Complexes with a Podand Schiff Base Containing a N4O3 Coordination Site

Abstract

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