Ion-interaction RP-HPLC separation of inorganic anions on porous graphitized carbon stationary phase. Comparison with ODS stationary phase

Maria Carla GENNARO, Emilio MARENGO, Valentina GIANOTTI

Research output: Contribution to journalArticle

Abstract

This paper shows how a porous graphitized stationary (PGC) phase can be modified to work in RP-HPLC ion-interaction reagent (IIR) mode. Aqueous solutions of alkylammonium ophosphate salts are used as IIRs and the analytes are the inorganic anions, iodide, iodate, bromide, bromate, nitrite, and nitrate. Comparisons with the results obtained under the same conditions for an ODS stationary phase show that the use of the PGC column permits extension, to IIR chromatography, in the pH range of only acidic values.

Original languageEnglish
Pages (from-to)2599-2613
Number of pages15
JournalJournal of Liquid Chromatography and Related Technologies
Volume23
Issue number17
DOIs
Publication statusPublished - 2000

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