Investigation of the electrochemical behavior and electronic structure of (M-butatriene)hexacarbonyldiiron complexes

Domenico Osella; Olimpia Gambino; Roberto Gobetto; Piero Zanello; Franco Laschi; Steven M. Owen; Catherine E. Housecroft

doi:10.1021/om00156a017

Investigation of the electrochemical behavior and electronic structure of (M-butatriene)hexacarbonyldiiron complexes

Domenico Osella
, Olimpia Gambino
, Roberto Gobetto
, Piero Zanello
, Franco Laschi
, Steven M. Owen
, Catherine E. Housecroft

Research output: Contribution to journal › Article › peer-review

Abstract

The redox chemistry of (jt-butatriene)hexacarbonyldiiron compounds, Ρβ₂(0Ο)₆(ΜΙΌ=0=0=0ΙΙΙΙ’), has been investigated by electrochemical and spectroscopic methods and Fenske-Hall quantum-chemical calculations. The sequence of the electrode processes has been postulated on the basis of the response of different electrochemical techniques, electron spin resonance (ESR) spectroscopy, and chemical tests. The butatriene chain, interacting with the bimetallic Fe₂(CO)₆ framework in a multicentered σ/π fashion, is able to stabilize the electrogenerated anions.

Original language	English
Pages (from-to)	1792-1797
Number of pages	6
Journal	Organometallics
Volume	9
Issue number	6
DOIs	https://doi.org/10.1021/om00156a017
Publication status	Published - 1990
Externally published	Yes

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title = "Investigation of the electrochemical behavior and electronic structure of (M-butatriene)hexacarbonyldiiron complexes",

abstract = "The redox chemistry of (jt-butatriene)hexacarbonyldiiron compounds, Ρβ2(0Ο)6(ΜΙΌ=0=0=0ΙΙΙΙ{\textquoteright}), has been investigated by electrochemical and spectroscopic methods and Fenske-Hall quantum-chemical calculations. The sequence of the electrode processes has been postulated on the basis of the response of different electrochemical techniques, electron spin resonance (ESR) spectroscopy, and chemical tests. The butatriene chain, interacting with the bimetallic Fe2(CO)6 framework in a multicentered σ/π fashion, is able to stabilize the electrogenerated anions.",

author = "Domenico Osella and Olimpia Gambino and Roberto Gobetto and Piero Zanello and Franco Laschi and Owen, \{Steven M.\} and Housecroft, \{Catherine E.\}",

year = "1990",

doi = "10.1021/om00156a017",

language = "English",

volume = "9",

pages = "1792--1797",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Investigation of the electrochemical behavior and electronic structure of (M-butatriene)hexacarbonyldiiron complexes

AU - Osella, Domenico

AU - Gambino, Olimpia

AU - Gobetto, Roberto

AU - Zanello, Piero

AU - Laschi, Franco

AU - Owen, Steven M.

AU - Housecroft, Catherine E.

PY - 1990

Y1 - 1990

N2 - The redox chemistry of (jt-butatriene)hexacarbonyldiiron compounds, Ρβ2(0Ο)6(ΜΙΌ=0=0=0ΙΙΙΙ’), has been investigated by electrochemical and spectroscopic methods and Fenske-Hall quantum-chemical calculations. The sequence of the electrode processes has been postulated on the basis of the response of different electrochemical techniques, electron spin resonance (ESR) spectroscopy, and chemical tests. The butatriene chain, interacting with the bimetallic Fe2(CO)6 framework in a multicentered σ/π fashion, is able to stabilize the electrogenerated anions.

AB - The redox chemistry of (jt-butatriene)hexacarbonyldiiron compounds, Ρβ2(0Ο)6(ΜΙΌ=0=0=0ΙΙΙΙ’), has been investigated by electrochemical and spectroscopic methods and Fenske-Hall quantum-chemical calculations. The sequence of the electrode processes has been postulated on the basis of the response of different electrochemical techniques, electron spin resonance (ESR) spectroscopy, and chemical tests. The butatriene chain, interacting with the bimetallic Fe2(CO)6 framework in a multicentered σ/π fashion, is able to stabilize the electrogenerated anions.

UR - https://www.scopus.com/pages/publications/33751553087

U2 - 10.1021/om00156a017

DO - 10.1021/om00156a017

M3 - Article

SN - 0276-7333

VL - 9

SP - 1792

EP - 1797

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Investigation of the electrochemical behavior and electronic structure of (M-butatriene)hexacarbonyldiiron complexes

Abstract

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