Interpretation of the terminal v(co) spectra of some M5 transition metal carbonyl clusters

S. F. A. KETTLE; E. DIANA; R. ROSSETTI; R. DELLA PERGOLA; Enrico BOCCALERI

doi:10.1016/S0020

Interpretation of the terminal v(co) spectra of some M5 transition metal carbonyl clusters

S. F. A. KETTLE
, E. DIANA
, R. ROSSETTI
, R. DELLA PERGOLA
, Enrico BOCCALERI

Department of Sustainable Development and Ecological Transition

Research output: Contribution to journal › Article › peer-review

Abstract

The n(CO) spectra of 31 M5 transition metal carbonyl clusters are interpreted in terms of the spherical harmonic and tensor harmonic models. It seems that the former is that which is generally applicable but that the splittings of the (spherical) P mode are larger than had previously been considered indicative of this model. An explanation in terms of the cluster asymmetry is suggested.

Original language	English
Pages (from-to)	32-38
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	350
DOIs	https://doi.org/10.1016/S0020
Publication status	Published - 2003

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10.1016/S0020

http://hdl.handle.net/11579/14707

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title = "Interpretation of the terminal v(co) spectra of some M5 transition metal carbonyl clusters",

abstract = "The n(CO) spectra of 31 M5 transition metal carbonyl clusters are interpreted in terms of the spherical harmonic and tensor harmonic models. It seems that the former is that which is generally applicable but that the splittings of the (spherical) P mode are larger than had previously been considered indicative of this model. An explanation in terms of the cluster asymmetry is suggested.",

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T1 - Interpretation of the terminal v(co) spectra of some M5 transition metal carbonyl clusters

AU - KETTLE, S. F. A.

AU - DIANA, E.

AU - ROSSETTI, R.

AU - PERGOLA, R. DELLA

AU - BOCCALERI, Enrico

PY - 2003

Y1 - 2003

N2 - The n(CO) spectra of 31 M5 transition metal carbonyl clusters are interpreted in terms of the spherical harmonic and tensor harmonic models. It seems that the former is that which is generally applicable but that the splittings of the (spherical) P mode are larger than had previously been considered indicative of this model. An explanation in terms of the cluster asymmetry is suggested.

AB - The n(CO) spectra of 31 M5 transition metal carbonyl clusters are interpreted in terms of the spherical harmonic and tensor harmonic models. It seems that the former is that which is generally applicable but that the splittings of the (spherical) P mode are larger than had previously been considered indicative of this model. An explanation in terms of the cluster asymmetry is suggested.

UR - https://iris.uniupo.it/handle/11579/14707

U2 - 10.1016/S0020

DO - 10.1016/S0020

M3 - Article

SN - 0020-1693

VL - 350

SP - 32

EP - 38

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Interpretation of the terminal v(co) spectra of some M5 transition metal carbonyl clusters

Abstract

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