Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe2Ir2(CO)12]2-, [HFe2Ir2(CO)12]- and [FeIr3(CO)12]-

S. F.A. Kettle; E. Diana; P. L. Stanghellini; R. Della Pergola

doi:10.1016/S0020-1693(00)92311-9

Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe₂Ir₂(CO)₁₂]^2-, [HFe₂Ir₂(CO)₁₂]^- and [FeIr₃(CO)₁₂]^-

S. F.A. Kettle, E. Diana, P. L. Stanghellini, R. Della Pergola

Research output: Contribution to journal › Article › peer-review

Abstract

The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.

Original language	English
Pages (from-to)	75-79
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	212
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(00)92311-9
Publication status	Published - Oct 1993
Externally published	Yes

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title = "Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe2Ir2(CO)12]2-, [HFe2Ir2(CO)12]- and [FeIr3(CO)12]-",

abstract = "The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.",

author = "Kettle, \{S. F.A.\} and E. Diana and Stanghellini, \{P. L.\} and Pergola, \{R. Della\}",

year = "1993",

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T1 - Interpretation of the ν(CO) vibrational spectra of cluster compounds

T2 - tetrahedral anions [Fe2Ir2(CO)12]2-, [HFe2Ir2(CO)12]- and [FeIr3(CO)12]-

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Stanghellini, P. L.

AU - Pergola, R. Della

PY - 1993/10

Y1 - 1993/10

N2 - The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.

AB - The analysis of the ν(CO) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibrational spectra of another. This parameter transferability, similar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.

UR - https://www.scopus.com/pages/publications/25344435763

U2 - 10.1016/S0020-1693(00)92311-9

DO - 10.1016/S0020-1693(00)92311-9

M3 - Article

SN - 0020-1693

VL - 212

SP - 75

EP - 79

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe₂Ir₂(CO)₁₂]^2-, [HFe₂Ir₂(CO)₁₂]^- and [FeIr₃(CO)₁₂]^-

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