Enhancement of the luminescence properties of eu (Iii) containing paramagnetic saponite clays

In this study, 1,10-phenanthroline molecules were introduced in the interlayer space of a paramagnetic synthetic saponite clay containing both Eu³⁺ and Gd³⁺ ions in structural positions. Two samples with different loading of phenanthroline dye were prepared. The resulting hybrid materials possessed improved optical emission properties due to an efficient antenna effect from the phenanthroline to the Eu³⁺ centers; this effect was demonstrated to be higher than the metal-to-metal Gd³⁺-Eu³⁺ energy transfer previously studied. Insights on the relaxometric properties in aqueous solution of the solids after incorporation of the antenna groups were also obtained through NMR relaxometric analyses.