Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

Gaetano Granozzi; Sergio Agnolin; Maurizio Casarin; Domenico Osella

doi:10.1016/S0022-328X(00)89184-6

Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

Gaetano Granozzi, Sergio Agnolin, Maurizio Casarin, Domenico Osella

Research output: Contribution to journal › Article › peer-review

Abstract

The He(I) excited photoelectron spectra of Co₃(CO)₉CY (where Y CH₃, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.

Original language	English
Pages (from-to)	C6-C8
Journal	Journal of Organometallic Chemistry
Volume	208
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)89184-6
Publication status	Published - 17 Mar 1981
Externally published	Yes

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title = "Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy",

abstract = "The He(I) excited photoelectron spectra of Co3(CO)9CY (where Y CH3, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.",

author = "Gaetano Granozzi and Sergio Agnolin and Maurizio Casarin and Domenico Osella",

year = "1981",

month = mar,

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doi = "10.1016/S0022-328X(00)89184-6",

language = "English",

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journal = "Journal of Organometallic Chemistry",

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T1 - Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

AU - Granozzi, Gaetano

AU - Agnolin, Sergio

AU - Casarin, Maurizio

AU - Osella, Domenico

PY - 1981/3/17

Y1 - 1981/3/17

N2 - The He(I) excited photoelectron spectra of Co3(CO)9CY (where Y CH3, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.

AB - The He(I) excited photoelectron spectra of Co3(CO)9CY (where Y CH3, F, Cl) are presented, and assignments of the bands to the ionization events are made on the basis of qualitative arguments. The photoelectron data agree with the representation of this cluster as an electron sink capable of π-interaction with the substituent Y.

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DO - 10.1016/S0022-328X(00)89184-6

M3 - Article

SN - 0022-328X

VL - 208

SP - C6-C8

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Electronic structure of some methinyltricobalt enneacarbonyls by means of ultraviolet photoelectron spectroscopy

Abstract

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