Electrochemical Investigation of a Series of Organotriruthenium Clusters

Piero Zanello; Silvio Aime; Domenico Osella

doi:10.1021/om00087a009

Electrochemical Investigation of a Series of Organotriruthenium Clusters

Piero Zanello
, Silvio Aime
, Domenico Osella

Research output: Contribution to journal › Article › peer-review

Abstract

The reduction and oxidation behavior of a series of organotriruthenium clusters, namely, HRu₃(CO)₉(μ₃-allenyl), HRu₃(CO)₉(μ₃-allyl), and HRu₃(CO)₉ (μ₃-alkynyl) complexes, is investigated by voltammetric techniques at mercury and platinum microelectrodes. The relationships between the resulting electrode potentials and both ¹³C NMR chemical shifts and v(CO) frequencies are presented.

Original language	English
Pages (from-to)	1374-1378
Number of pages	5
Journal	Organometallics
Volume	3
Issue number	9
DOIs	https://doi.org/10.1021/om00087a009
Publication status	Published - Dec 1984
Externally published	Yes

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title = "Electrochemical Investigation of a Series of Organotriruthenium Clusters",

abstract = "The reduction and oxidation behavior of a series of organotriruthenium clusters, namely, HRu3(CO)9(μ3-allenyl), HRu3(CO)9(μ3-allyl), and HRu3(CO)9 (μ3-alkynyl) complexes, is investigated by voltammetric techniques at mercury and platinum microelectrodes. The relationships between the resulting electrode potentials and both 13C NMR chemical shifts and v(CO) frequencies are presented.",

author = "Piero Zanello and Silvio Aime and Domenico Osella",

year = "1984",

month = dec,

doi = "10.1021/om00087a009",

language = "English",

volume = "3",

pages = "1374--1378",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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T1 - Electrochemical Investigation of a Series of Organotriruthenium Clusters

AU - Zanello, Piero

AU - Aime, Silvio

AU - Osella, Domenico

PY - 1984/12

Y1 - 1984/12

N2 - The reduction and oxidation behavior of a series of organotriruthenium clusters, namely, HRu3(CO)9(μ3-allenyl), HRu3(CO)9(μ3-allyl), and HRu3(CO)9 (μ3-alkynyl) complexes, is investigated by voltammetric techniques at mercury and platinum microelectrodes. The relationships between the resulting electrode potentials and both 13C NMR chemical shifts and v(CO) frequencies are presented.

AB - The reduction and oxidation behavior of a series of organotriruthenium clusters, namely, HRu3(CO)9(μ3-allenyl), HRu3(CO)9(μ3-allyl), and HRu3(CO)9 (μ3-alkynyl) complexes, is investigated by voltammetric techniques at mercury and platinum microelectrodes. The relationships between the resulting electrode potentials and both 13C NMR chemical shifts and v(CO) frequencies are presented.

UR - https://www.scopus.com/pages/publications/0039005333

U2 - 10.1021/om00087a009

DO - 10.1021/om00087a009

M3 - Article

SN - 0276-7333

VL - 3

SP - 1374

EP - 1378

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Electrochemical Investigation of a Series of Organotriruthenium Clusters

Abstract

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