Electrochemical behaviour of the electronically and coordinatively unsaturated cluster [Os3(γ-H)(CO)8{Ph2PCH2P(Ph)C6H4})]

Domenico Osella, Mauro Ravera, Anthony K. Smith, A. Jane Mathews, Piero Zanello

Research output: Contribution to journalArticlepeer-review

Abstract

The electrochemical behaviour of the unsaturated cluster Os3(H)(CO)8[Ph2PCH2P(Ph)C6H4] has been studied by electrochemical and spectroscopic methods. The transformations of the very reactive title compound into the saturated cluster Os3(H)(CO)9[Ph2PCH2P(Ph)C6H4] and Os3(CO)10(Ph2PCH2PPh2] by CO addition has been followed step-by-step by cyclic voltammetry.

Original languageEnglish
Pages (from-to)255-261
Number of pages7
JournalJournal of Organometallic Chemistry
Volume423
Issue number2
DOIs
Publication statusPublished - 21 Jan 1992
Externally publishedYes

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