Determination of Trace Europium by Adsorptive Cathodic Stripping Voltammetry after Complexation with Cupferron

Ornella Abollino; Maurizio Aceto; Edoardo Mentasti; Corrado Sarzanini; Constant M.G. Van Den Berg

doi:10.1002/elan.1140090603

Determination of Trace Europium by Adsorptive Cathodic Stripping Voltammetry after Complexation with Cupferron

Ornella Abollino
, Maurizio Aceto
, Edoardo Mentasti
, Corrado Sarzanini
, Constant M.G. Van Den Berg

Research output: Contribution to journal › Article › peer-review

Abstract

This article describes the determination of Eu by adsorptive cathodic stripping voltammetry after complexation with N-nitroso-N-phenylhydroxylamine (cupferron). The accumulation of the complex at the HMDE was performed at 0.0 V and the subsequent potential scan was made in the square wave mode. The analyte signal occurred at -0.88 V. The detection limit is 0.06 nmol dm^-3. The effect of instrumental and chemical parameters on the peak height and potential was investigated. The same technique can be used for the determination of ytterbium and of the other rare earth elements (REEs) after separation.

Original language	English
Pages (from-to)	444-448
Number of pages	5
Journal	Electroanalysis
Volume	9
Issue number	6
DOIs	https://doi.org/10.1002/elan.1140090603
Publication status	Published - Apr 1997
Externally published	Yes

Keywords

Cathodic stripping voltammetry
Cupferron
Europium determination
Lanthanides
Rare earth elements
Square wave voltammetry
Ytterbium determination

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10.1002/elan.1140090603

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title = "Determination of Trace Europium by Adsorptive Cathodic Stripping Voltammetry after Complexation with Cupferron",

abstract = "This article describes the determination of Eu by adsorptive cathodic stripping voltammetry after complexation with N-nitroso-N-phenylhydroxylamine (cupferron). The accumulation of the complex at the HMDE was performed at 0.0 V and the subsequent potential scan was made in the square wave mode. The analyte signal occurred at -0.88 V. The detection limit is 0.06 nmol dm-3. The effect of instrumental and chemical parameters on the peak height and potential was investigated. The same technique can be used for the determination of ytterbium and of the other rare earth elements (REEs) after separation.",

keywords = "Cathodic stripping voltammetry, Cupferron, Europium determination, Lanthanides, Rare earth elements, Square wave voltammetry, Ytterbium determination",

author = "Ornella Abollino and Maurizio Aceto and Edoardo Mentasti and Corrado Sarzanini and \{Van Den Berg\}, \{Constant M.G.\}",

year = "1997",

month = apr,

doi = "10.1002/elan.1140090603",

language = "English",

volume = "9",

pages = "444--448",

journal = "Electroanalysis",

issn = "1040-0397",

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T1 - Determination of Trace Europium by Adsorptive Cathodic Stripping Voltammetry after Complexation with Cupferron

AU - Abollino, Ornella

AU - Aceto, Maurizio

AU - Mentasti, Edoardo

AU - Sarzanini, Corrado

AU - Van Den Berg, Constant M.G.

PY - 1997/4

Y1 - 1997/4

N2 - This article describes the determination of Eu by adsorptive cathodic stripping voltammetry after complexation with N-nitroso-N-phenylhydroxylamine (cupferron). The accumulation of the complex at the HMDE was performed at 0.0 V and the subsequent potential scan was made in the square wave mode. The analyte signal occurred at -0.88 V. The detection limit is 0.06 nmol dm-3. The effect of instrumental and chemical parameters on the peak height and potential was investigated. The same technique can be used for the determination of ytterbium and of the other rare earth elements (REEs) after separation.

AB - This article describes the determination of Eu by adsorptive cathodic stripping voltammetry after complexation with N-nitroso-N-phenylhydroxylamine (cupferron). The accumulation of the complex at the HMDE was performed at 0.0 V and the subsequent potential scan was made in the square wave mode. The analyte signal occurred at -0.88 V. The detection limit is 0.06 nmol dm-3. The effect of instrumental and chemical parameters on the peak height and potential was investigated. The same technique can be used for the determination of ytterbium and of the other rare earth elements (REEs) after separation.

KW - Cathodic stripping voltammetry

KW - Cupferron

KW - Europium determination

KW - Lanthanides

KW - Rare earth elements

KW - Square wave voltammetry

KW - Ytterbium determination

UR - https://www.scopus.com/pages/publications/0013278354

U2 - 10.1002/elan.1140090603

DO - 10.1002/elan.1140090603

M3 - Article

SN - 1040-0397

VL - 9

SP - 444

EP - 448

JO - Electroanalysis

JF - Electroanalysis

IS - 6

ER -

Determination of Trace Europium by Adsorptive Cathodic Stripping Voltammetry after Complexation with Cupferron

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Keywords

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