Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

Manfredi Caruso; Manuel Petroselli; Massimo Cametti

doi:10.1002/slct.202103792

Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

Manfredi Caruso, Manuel Petroselli, Massimo Cametti

Research output: Contribution to journal › Article › peer-review

Abstract

Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.

Original language	English
Pages (from-to)	12975-12980
Number of pages	6
Journal	ChemistrySelect
Volume	6
Issue number	45
DOIs	https://doi.org/10.1002/slct.202103792
Publication status	Published - 6 Dec 2021
Externally published	Yes

Keywords

N-hydroxylphthalimide (NHPI)
bond dissociation energy
cyclization reaction
ionic liquids
zeolitic imidazolate frameworks (ZIF)

Access to Document

10.1002/slct.202103792

Cite this

@article{4139e376269b499885b2025a84368a6c,

title = "Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**",

abstract = "Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.",

keywords = "N-hydroxylphthalimide (NHPI), bond dissociation energy, cyclization reaction, ionic liquids, zeolitic imidazolate frameworks (ZIF)",

author = "Manfredi Caruso and Manuel Petroselli and Massimo Cametti",

note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",

year = "2021",

month = dec,

day = "6",

doi = "10.1002/slct.202103792",

language = "English",

volume = "6",

pages = "12975--12980",

journal = "ChemistrySelect",

issn = "2365-6549",

publisher = "Wiley-Blackwell Publishing Ltd",

number = "45",

}

TY - JOUR

T1 - Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

AU - Caruso, Manfredi

AU - Petroselli, Manuel

AU - Cametti, Massimo

PY - 2021/12/6

Y1 - 2021/12/6

N2 - Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.

AB - Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.

KW - N-hydroxylphthalimide (NHPI)

KW - bond dissociation energy

KW - cyclization reaction

KW - ionic liquids

KW - zeolitic imidazolate frameworks (ZIF)

UR - https://www.scopus.com/pages/publications/85120455533

U2 - 10.1002/slct.202103792

DO - 10.1002/slct.202103792

M3 - Article

SN - 2365-6549

VL - 6

SP - 12975

EP - 12980

JO - ChemistrySelect

JF - ChemistrySelect

IS - 45

ER -

Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this