Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

M. Caruso; MANUEL PETROSELLI; M. Cametti

doi:10.1002/slct.202103792

Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

M. Caruso, MANUEL PETROSELLI, M. Cametti

Department of Science and Technological Innovation

Research output: Contribution to journal › Article

Abstract

Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.

Original language	English
Pages (from-to)	12975-12980
Number of pages	6
Journal	ChemistrySelect
Volume	6
Issue number	45
DOIs	https://doi.org/10.1002/slct.202103792
Publication status	Published - 2021

Keywords

bond dissociation energy
cyclization reaction
ionic liquids
N-hydroxylphthalimide (NHPI)
zeolitic imidazolate frameworks (ZIF)

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10.1002/slct.202103792

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title = "Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**",

abstract = "Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.",

keywords = "bond dissociation energy, cyclization reaction, ionic liquids, N-hydroxylphthalimide (NHPI), zeolitic imidazolate frameworks (ZIF), bond dissociation energy, cyclization reaction, ionic liquids, N-hydroxylphthalimide (NHPI), zeolitic imidazolate frameworks (ZIF)",

author = "M. Caruso and MANUEL PETROSELLI and M. Cametti",

year = "2021",

doi = "10.1002/slct.202103792",

language = "English",

volume = "6",

pages = "12975--12980",

journal = "ChemistrySelect",

issn = "2365-6549",

publisher = "Wiley-Blackwell Publishing Ltd",

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TY - JOUR

T1 - Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

AU - Caruso, M.

AU - PETROSELLI, MANUEL

AU - Cametti, M.

PY - 2021

Y1 - 2021

N2 - Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.

AB - Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO−H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.

KW - bond dissociation energy

KW - cyclization reaction

KW - ionic liquids

KW - N-hydroxylphthalimide (NHPI)

KW - zeolitic imidazolate frameworks (ZIF)

KW - bond dissociation energy

KW - cyclization reaction

KW - ionic liquids

KW - N-hydroxylphthalimide (NHPI)

KW - zeolitic imidazolate frameworks (ZIF)

UR - https://iris.uniupo.it/handle/null

U2 - 10.1002/slct.202103792

DO - 10.1002/slct.202103792

M3 - Article

SN - 2365-6549

VL - 6

SP - 12975

EP - 12980

JO - ChemistrySelect

JF - ChemistrySelect

IS - 45

ER -

Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

Abstract

Keywords

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