Dehydrative glycosylation with the Hendrickson reagent

M MOSSOTTI; Luigi PANZA

Dehydrative glycosylation with the Hendrickson reagent

M MOSSOTTI
, Luigi PANZA

Department of Pharmaceutical Sciences

Research output: Contribution to journal › Article

Abstract

The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by ¹⁸O labeling of anomeric OH.

Original language	English
Pages (from-to)	9122-9126
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	76
Publication status	Published - 2011

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title = "Dehydrative glycosylation with the Hendrickson reagent",

abstract = "The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.",

author = "M MOSSOTTI and Luigi PANZA",

year = "2011",

language = "English",

volume = "76",

pages = "9122--9126",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - Dehydrative glycosylation with the Hendrickson reagent

AU - MOSSOTTI, M

AU - PANZA, Luigi

PY - 2011

Y1 - 2011

N2 - The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.

AB - The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.

UR - https://iris.uniupo.it/handle/11579/15651

M3 - Article

SN - 0022-3263

VL - 76

SP - 9122

EP - 9126

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

ER -

Dehydrative glycosylation with the Hendrickson reagent

Abstract

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