Dehydrative Alkylation of Alcohols with Triethyl Methanetricarboxylate under Mitsunobu Conditions

G Cravotto; Giovanni Battista GIOVENZANA; G Palmisano; M. Sisti

doi:10.1016/0040-4020(96)00781-8

Dehydrative Alkylation of Alcohols with Triethyl Methanetricarboxylate under Mitsunobu Conditions

G Cravotto
, Giovanni Battista GIOVENZANA
, G Palmisano
, M. Sisti

Department of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.

Original language	English
Pages (from-to)	13007-13016
Number of pages	10
Journal	Tetrahedron
Volume	52
Issue number	40
DOIs	https://doi.org/10.1016/0040-4020(96)00781-8
Publication status	Published - 1996

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10.1016/0040-4020(96)00781-8

http://hdl.handle.net/11579/4686

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@article{ac3013327f5c4395aa0b15de023ef68f,

title = "Dehydrative Alkylation of Alcohols with Triethyl Methanetricarboxylate under Mitsunobu Conditions",

abstract = "Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.",

author = "G Cravotto and GIOVENZANA, \{Giovanni Battista\} and G Palmisano and M. Sisti",

year = "1996",

doi = "10.1016/0040-4020(96)00781-8",

language = "English",

volume = "52",

pages = "13007--13016",

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T1 - Dehydrative Alkylation of Alcohols with Triethyl Methanetricarboxylate under Mitsunobu Conditions

AU - Cravotto, G

AU - GIOVENZANA, Giovanni Battista

AU - Palmisano, G

AU - Sisti, M.

PY - 1996

Y1 - 1996

N2 - Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.

AB - Triethyl methanetricarboxylate (TEMT) can be mildly alkylated by primary, benzylic and allylic alcohols under classical Mitsunobu conditions, in fair to good yields. The utility of TEMT in organic synthesis as a diethyl malonate surrogate is reported.

UR - https://iris.uniupo.it/handle/11579/4686

U2 - 10.1016/0040-4020(96)00781-8

DO - 10.1016/0040-4020(96)00781-8

M3 - Article

SN - 0040-4020

VL - 52

SP - 13007

EP - 13016

JO - Tetrahedron

JF - Tetrahedron

IS - 40

ER -

Dehydrative Alkylation of Alcohols with Triethyl Methanetricarboxylate under Mitsunobu Conditions

Abstract

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