Coordination chemistry of nitrile and amino pendant arm derivatives of [9]aneN2S and [9]aneNS2 with PdII and CuII

Massimiliano Arca; Alexander J. Blake; Vito Lippolis; Daniela R. Montesu; Jonathan McMaster; Lorenzo Tei; Martin Schröder

doi:10.1002/ejic.200390160

Coordination chemistry of nitrile and amino pendant arm derivatives of [9]aneN₂S and [9]aneN_S2 with Pd^II and Cu^II

Massimiliano Arca, Alexander J. Blake, Vito Lippolis, Daniela R. Montesu, Jonathan McMaster, Lorenzo Tei, Martin Schröder

Research output: Contribution to journal › Article › peer-review

Abstract

Palladium(II) and copper(II) complexes [Pd(L¹)Cl₂], [Pd(L³)-Cl₂], [Cu(L¹)Cl₂], [Cu(L³)Cl₂], [Pd(L²)][BF₄]₂, [Pd(L⁴)Cl]-BF₄, [Cu(L²)][NO₃]₂ and [Cu(L⁴)Cl]PF₆ of the nitrile (L¹ and L³) and amino (L² and L⁴) pendant arm derivatives of 1-thia-4,7-diazacyclononane ([9]aneN₂S) and 7-aza-1,4-dithiacyclononane ([9]aneNS₂) have been prepared and fully characterised. In each case, a square-pyramidal coordination sphere is observed at both metal ions with either one or two Cl^- anions completing the donor set. The tridentate nine-membered macrocyclic moiety adopts a [333] conformation in all the complexes obtained. The five-membered chelate rings involving the donor atoms of the basal plane adopt a gauche configuration with very similar degrees of puckering. The "innocent" nitrile pendant arms in L¹ and L³ do not bind to the metal ions, but still appear to influence the binding of the tridentate macrocyclic frameworks via the tertiary amine sites.

Original language	English
Pages (from-to)	1232-1241
Number of pages	10
Journal	European Journal of Inorganic Chemistry
Issue number	6
DOIs	https://doi.org/10.1002/ejic.200390160
Publication status	Published - Mar 2003
Externally published	Yes

Keywords

Copper
Macrocycles
N ligands
Palladium
S ligands

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@article{8c67b7ad12de4d22a4eff042810b9328,

title = "Coordination chemistry of nitrile and amino pendant arm derivatives of [9]aneN2S and [9]aneNS2 with PdII and CuII",

abstract = "Palladium(II) and copper(II) complexes [Pd(L1)Cl2], [Pd(L3)-Cl2], [Cu(L1)Cl2], [Cu(L3)Cl2], [Pd(L2)][BF4]2, [Pd(L4)Cl]-BF4, [Cu(L2)][NO3]2 and [Cu(L4)Cl]PF6 of the nitrile (L1 and L3) and amino (L2 and L4) pendant arm derivatives of 1-thia-4,7-diazacyclononane ([9]aneN2S) and 7-aza-1,4-dithiacyclononane ([9]aneNS2) have been prepared and fully characterised. In each case, a square-pyramidal coordination sphere is observed at both metal ions with either one or two Cl- anions completing the donor set. The tridentate nine-membered macrocyclic moiety adopts a [333] conformation in all the complexes obtained. The five-membered chelate rings involving the donor atoms of the basal plane adopt a gauche configuration with very similar degrees of puckering. The {"}innocent{"} nitrile pendant arms in L1 and L3 do not bind to the metal ions, but still appear to influence the binding of the tridentate macrocyclic frameworks via the tertiary amine sites.",

keywords = "Copper, Macrocycles, N ligands, Palladium, S ligands",

author = "Massimiliano Arca and Blake, \{Alexander J.\} and Vito Lippolis and Montesu, \{Daniela R.\} and Jonathan McMaster and Lorenzo Tei and Martin Schr{\"o}der",

year = "2003",

month = mar,

doi = "10.1002/ejic.200390160",

language = "English",

pages = "1232--1241",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "6",

}

TY - JOUR

T1 - Coordination chemistry of nitrile and amino pendant arm derivatives of [9]aneN2S and [9]aneNS2 with PdII and CuII

AU - Arca, Massimiliano

AU - Blake, Alexander J.

AU - Lippolis, Vito

AU - Montesu, Daniela R.

AU - McMaster, Jonathan

AU - Tei, Lorenzo

AU - Schröder, Martin

PY - 2003/3

Y1 - 2003/3

N2 - Palladium(II) and copper(II) complexes [Pd(L1)Cl2], [Pd(L3)-Cl2], [Cu(L1)Cl2], [Cu(L3)Cl2], [Pd(L2)][BF4]2, [Pd(L4)Cl]-BF4, [Cu(L2)][NO3]2 and [Cu(L4)Cl]PF6 of the nitrile (L1 and L3) and amino (L2 and L4) pendant arm derivatives of 1-thia-4,7-diazacyclononane ([9]aneN2S) and 7-aza-1,4-dithiacyclononane ([9]aneNS2) have been prepared and fully characterised. In each case, a square-pyramidal coordination sphere is observed at both metal ions with either one or two Cl- anions completing the donor set. The tridentate nine-membered macrocyclic moiety adopts a [333] conformation in all the complexes obtained. The five-membered chelate rings involving the donor atoms of the basal plane adopt a gauche configuration with very similar degrees of puckering. The "innocent" nitrile pendant arms in L1 and L3 do not bind to the metal ions, but still appear to influence the binding of the tridentate macrocyclic frameworks via the tertiary amine sites.

AB - Palladium(II) and copper(II) complexes [Pd(L1)Cl2], [Pd(L3)-Cl2], [Cu(L1)Cl2], [Cu(L3)Cl2], [Pd(L2)][BF4]2, [Pd(L4)Cl]-BF4, [Cu(L2)][NO3]2 and [Cu(L4)Cl]PF6 of the nitrile (L1 and L3) and amino (L2 and L4) pendant arm derivatives of 1-thia-4,7-diazacyclononane ([9]aneN2S) and 7-aza-1,4-dithiacyclononane ([9]aneNS2) have been prepared and fully characterised. In each case, a square-pyramidal coordination sphere is observed at both metal ions with either one or two Cl- anions completing the donor set. The tridentate nine-membered macrocyclic moiety adopts a [333] conformation in all the complexes obtained. The five-membered chelate rings involving the donor atoms of the basal plane adopt a gauche configuration with very similar degrees of puckering. The "innocent" nitrile pendant arms in L1 and L3 do not bind to the metal ions, but still appear to influence the binding of the tridentate macrocyclic frameworks via the tertiary amine sites.

KW - Copper

KW - Macrocycles

KW - N ligands

KW - Palladium

KW - S ligands

UR - https://www.scopus.com/pages/publications/0037356795

U2 - 10.1002/ejic.200390160

DO - 10.1002/ejic.200390160

M3 - Article

SN - 1434-1948

SP - 1232

EP - 1241

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 6

ER -

Coordination chemistry of nitrile and amino pendant arm derivatives of [9]aneN₂S and [9]aneN_S2 with Pd^II and Cu^II

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Keywords

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