A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

Antonio Scafuri; Riccardo Vivani; FABIO CARNIATO; LORENZO TEI; Mauro BOTTA; Marco Taddei; Ferdinando Costantino

doi:10.1039/c5dt02808f

A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

Antonio Scafuri, Riccardo Vivani, FABIO CARNIATO, LORENZO TEI, Mauro BOTTA, Marco Taddei, Ferdinando Costantino

Department of Science and Technological Innovation

Research output: Contribution to journal › Article › peer-review

Abstract

Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

Original language	English
Pages (from-to)	19072-19075
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	44
DOIs	https://doi.org/10.1039/c5dt02808f
Publication status	Published - 2015

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10.1039/c5dt02808f

http://hdl.handle.net/11579/69971

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title = "A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework",

abstract = "Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.",

author = "Antonio Scafuri and Riccardo Vivani and FABIO CARNIATO and LORENZO TEI and Mauro BOTTA and Marco Taddei and Ferdinando Costantino",

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year = "2015",

doi = "10.1039/c5dt02808f",

language = "English",

volume = "44",

pages = "19072--19075",

journal = "Dalton Transactions",

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T1 - A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

AU - Scafuri, Antonio

AU - Vivani, Riccardo

AU - CARNIATO, FABIO

AU - TEI, LORENZO

AU - BOTTA, Mauro

AU - Taddei, Marco

AU - Costantino, Ferdinando

PY - 2015

Y1 - 2015

N2 - Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

AB - Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and 1H NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

UR - https://iris.uniupo.it/handle/11579/69971

U2 - 10.1039/c5dt02808f

DO - 10.1039/c5dt02808f

M3 - Article

SN - 1477-9234

VL - 44

SP - 19072

EP - 19075

JO - Dalton Transactions

JF - Dalton Transactions

IS - 44

ER -

A structural and 1H NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

Abstract

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