A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

D. Espa; L. Pilia; L. Marchiò; F. Artizzu; G. Di Carlo; D. Marinotto; A. Serpe; F. Tessore; P. Deplano

doi:10.1039/c6dt02911f

A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

D. Espa
, L. Pilia
, L. Marchiò
, F. Artizzu
, G. Di Carlo
, D. Marinotto
, A. Serpe
, F. Tessore
, P. Deplano

Research output: Contribution to journal › Article › peer-review

Abstract

A film of [Pd(R₂pipdt)(dmit)] (1), where R₂pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione-dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.

Original language	English
Pages (from-to)	17431-17438
Number of pages	8
Journal	Dalton Transactions
Volume	45
Issue number	43
DOIs	https://doi.org/10.1039/c6dt02911f
Publication status	Published - 2016
Externally published	Yes

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title = "A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores",

abstract = "A film of [Pd(R2pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione-dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.",

author = "D. Espa and L. Pilia and L. Marchi{\`o} and F. Artizzu and \{Di Carlo\}, G. and D. Marinotto and A. Serpe and F. Tessore and P. Deplano",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6dt02911f",

language = "English",

volume = "45",

pages = "17431--17438",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "43",

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TY - JOUR

T1 - A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

AU - Espa, D.

AU - Pilia, L.

AU - Marchiò, L.

AU - Artizzu, F.

AU - Di Carlo, G.

AU - Marinotto, D.

AU - Serpe, A.

AU - Tessore, F.

AU - Deplano, P.

PY - 2016

Y1 - 2016

N2 - A film of [Pd(R2pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione-dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.

AB - A film of [Pd(R2pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione-dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.

UR - https://www.scopus.com/pages/publications/84994316650

U2 - 10.1039/c6dt02911f

DO - 10.1039/c6dt02911f

M3 - Article

SN - 1477-9226

VL - 45

SP - 17431

EP - 17438

JO - Dalton Transactions

JF - Dalton Transactions

IS - 43

ER -

A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

Abstract

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