A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os3 carbonyl clusters

S. F.A. Kettle; E. Diana; R. Rossetti; P. L. Stanghellini

doi:10.1016/S0020-1693(01)00453-4

A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os₃ carbonyl clusters

S. F.A. Kettle
, E. Diana
, R. Rossetti
, P. L. Stanghellini

Research output: Contribution to journal › Article › peer-review

Abstract

The ν(M-M) Raman spectra of some twenty doubly bridged Os₃ carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm^-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.

Original language	English
Pages (from-to)	75-82
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	319
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00453-4
Publication status	Published - 16 Jul 2001
Externally published	Yes

Keywords

Carbonyl complexes
Cluster complexes
Osmium complexes
Raman spectroscopy

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10.1016/S0020-1693(01)00453-4

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title = "A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os3 carbonyl clusters",

abstract = "The ν(M-M) Raman spectra of some twenty doubly bridged Os3 carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.",

keywords = "Carbonyl complexes, Cluster complexes, Osmium complexes, Raman spectroscopy",

author = "Kettle, \{S. F.A.\} and E. Diana and R. Rossetti and Stanghellini, \{P. L.\}",

year = "2001",

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T1 - A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os3 carbonyl clusters

AU - Kettle, S. F.A.

AU - Diana, E.

AU - Rossetti, R.

AU - Stanghellini, P. L.

PY - 2001/7/16

Y1 - 2001/7/16

N2 - The ν(M-M) Raman spectra of some twenty doubly bridged Os3 carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.

AB - The ν(M-M) Raman spectra of some twenty doubly bridged Os3 carbonyl clusters are interpreted using a new model in which the mass of all the ligands is incorporated. The frequencies are fitted remarkably well; the average standard deviation is 2.1 cm-1. The data from the model seems to have some physical reality in that when applied to the calculation of some structural parameters (Os-Os distance and Os-Os-Os angle) it gives reasonable results.

KW - Carbonyl complexes

KW - Cluster complexes

KW - Osmium complexes

KW - Raman spectroscopy

UR - https://www.scopus.com/pages/publications/0035898831

U2 - 10.1016/S0020-1693(01)00453-4

DO - 10.1016/S0020-1693(01)00453-4

M3 - Article

SN - 0020-1693

VL - 319

SP - 75

EP - 82

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

A modified plastic cluster model for the interpretation of the ν(M-M) spectra of some bridged Os₃ carbonyl clusters

Abstract

Keywords

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